Knowledge Resource Center for Ecological Environment in Arid Area
DOI | 10.1016/j.indcrop.2016.02.054 |
Fast high resolution Orbitrap MS fingerprinting of the resin of Heliotropium taltalense Phil. from the Atacama Desert | |
Simirgiotis, Mario J.1; Quispe, Cristina2; Borquez, Jorge1; Schmeda-Hirschmann, Guillermo3; Avendano, Maria1; Sepulveda, Beatriz4; Winterhalter, Peter5 | |
通讯作者 | Simirgiotis, Mario J. |
来源期刊 | INDUSTRIAL CROPS AND PRODUCTS |
ISSN | 0926-6690 |
EISSN | 1872-633X |
出版年 | 2016 |
卷号 | 85页码:159-166 |
英文摘要 | Mass spectrometry has become the preferred analytical technique to characterize organic compounds in biological samples because of its sensitivity and selectivity. Hybrid UHPLC coupled to Orbitrap mass analyzer is an innovative state of the art technology that allows fast and accurate metabolomic analyses. In this work, Several flavanones, flavonols, and benzoic acid geranyl derivatives were rapidly identified in the resinous exudate of Heliotropium taltalense Phil., an endemic species growing in Paposo valley northern Chile, by means of ultrahigh resolution liquid chromatography Orbitrap MS MS analysis (UHPLC-PDA-OT-MS). The relationship between the compounds detected and some biosynthetic pathways or mechanisms of formation of the geranyl derivatives are proposed. Furthermore, some common flavonoids and the new compound 3,4-dihydroxy-5-geranyl-benzoic acid were isolated from the plant resin using liquid liquid high speed countercurrent chromatography (HPCCC). The new structure was elucidated by spectroscopic means (NMR). (C) 2016 Elsevier B.V. All rights reserved. |
英文关键词 | UHPLC Orbitrap High resolution MS analysis New compound Benzoic acid geranyl derivatives Flavonoids HPCCC Chilean plants Heliotropium NMR |
类型 | Article |
语种 | 英语 |
国家 | Chile ; Germany |
收录类别 | SCI-E |
WOS记录号 | WOS:000374361100017 |
WOS关键词 | BENZOIC-ACID DERIVATIVES ; COUNTERCURRENT CHROMATOGRAPHY ; ANTIOXIDANT ACTIVITY ; PHENOLIC-COMPOUNDS ; PIPER ; FILIFOLINOL ; EXUDATE ; CONSTITUENTS ; CAPACITY |
WOS类目 | Agricultural Engineering ; Agronomy |
WOS研究方向 | Agriculture |
资源类型 | 期刊论文 |
条目标识符 | http://119.78.100.177/qdio/handle/2XILL650/193591 |
作者单位 | 1.Univ Antofagasta, Fac Ciencias Basicas, Dept Quim, Casilla 170, Antofagasta 1240000, Chile; 2.Univ Arturo Prat, Fac Ciencias Salud, Casilla 121, Iquique 1110939, Chile; 3.Univ Talca, Lab Quim Prod Nat, Inst Quim Recursos Nat, Casilla 747, Talca 3460000, Chile; 4.Univ Andres Bello, Dept Ciencias Quim, Campus Vina del Mar, Vina Del Mar 2520000, Chile; 5.Tech Univ Carolo Wilhelmina Braunschweig, Inst Food Chem, Schleinitz Str 20, D-38106 Braunschweig, Germany |
推荐引用方式 GB/T 7714 | Simirgiotis, Mario J.,Quispe, Cristina,Borquez, Jorge,et al. Fast high resolution Orbitrap MS fingerprinting of the resin of Heliotropium taltalense Phil. from the Atacama Desert[J],2016,85:159-166. |
APA | Simirgiotis, Mario J..,Quispe, Cristina.,Borquez, Jorge.,Schmeda-Hirschmann, Guillermo.,Avendano, Maria.,...&Winterhalter, Peter.(2016).Fast high resolution Orbitrap MS fingerprinting of the resin of Heliotropium taltalense Phil. from the Atacama Desert.INDUSTRIAL CROPS AND PRODUCTS,85,159-166. |
MLA | Simirgiotis, Mario J.,et al."Fast high resolution Orbitrap MS fingerprinting of the resin of Heliotropium taltalense Phil. from the Atacama Desert".INDUSTRIAL CROPS AND PRODUCTS 85(2016):159-166. |
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