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Although the semi-arid region of Brazil appears to be homogeneous due to drought conditions, there is a great deal of variability in climatic elements in the region, so that the definition of homogeneous regions will provide the deployment of measures appropriate for each locality. However, the limited information on climatic parameters in the region makes it difficult to define these regions. This problem can, however, be alleviated by the use of entropy theory. Therefore, this study aimed to investigate the potential of the theory to identify hydrologically homogeneous regions for conditions of the semi-arid region of Brazil. Entropy-based Disorder Index (DI) data were computed, based on monthly precipitation and monthly water balance (precipitation - reference evapotranspiration) for 290 gauge stations. For defining homogeneous regions, cluster analysis was utilized, using the data on geographical information about rain gauges (latitude and longitude), annual precipitation, annual water balance, coefficient of skewness, coefficient of kurtosis and DI. The identification of homogeneous regions in the Brazilian semi-arid region was only possible when the grouping of stations was performed, based on DI for precipitation and latitude. Results showed the definition of seven homogeneous regions in the semi-arid region of Brazil.