Arid
DOI10.1016/j.gca.2016.03.012
Deposition, accumulation, and alteration of Cl-, NO3-, ClO4- and ClO3- salts in a hyper-arid polar environment: Mass balance and isotopic constraints
Jackson, Andrew1; Davila, Alfonso F.2; Bohlke, John Karl3; Sturchio, Neil C.4; Sevanthi, Ritesh1; Estrada, Nubia1; Brundrett, Maeghan1; Lacelle, Denis5; McKay, Christopher P.6; Poghosyan, Armen7; Pollard, Wayne8; Zacny, Kris9
通讯作者Jackson, Andrew
来源期刊GEOCHIMICA ET COSMOCHIMICA ACTA
ISSN0016-7037
EISSN1872-9533
出版年2016
卷号182页码:197-215
英文摘要

The salt fraction in permafrost soils/sediments of the McMurdo Dry Valleys (MDV) of Antarctica can be used as a proxy for cold desert geochemical processes and paleoclimate reconstruction. Previous analyses of the salt fraction in MDV permafrost soils have largely been conducted in coastal regions where permafrost soils are variably affected by aqueous processes and mixed inputs from marine and stratospheric sources. We expand upon this work by evaluating permafrost soil/sediments in University Valley, located in the ultraxerous zone where both liquid water transport and marine influences are minimal. We determined the abundances of Cl-, NO3-, ClO4- and ClO3- in dry and ice-cemented soil/sediments, snow and glacier ice, and also characterized Cl- and NO3- isotopically. The data are not consistent with salt deposition in a sublimation till, nor with nuclear weapon testing fall-out, and instead point to a dominantly stratospheric source and to varying degrees of post depositional transformation depending on the substrate, from minimal alteration in bare soils to significant alteration (photodegradation and/or volatilization) in snow and glacier ice. Ionic abundances in the dry permafrost layer indicate limited vertical transport under the current climate conditions, likely due to percolation of snowmelt. Subtle changes in ClO4-/NO3- ratios and NO3- isotopic composition with depth and location may reflect both transport related fractionation and depositional history. Low molar ratios of ClO3-/ClO4- in surface soils compared to deposition and other arid systems suggest significant post depositional loss of ClO3-, possibly due to reduction by iron minerals, which may have important implications for oxy-chlorine species on Mars. Salt accumulation varies with distance along the valley and apparent accumulation times based on multiple methods range from similar to 10 to 30 kyr near the glacier to 70-200 kyr near the valley mouth. The relatively young age of the salts and relatively low and homogeneous anion concentrations in the ice-cemented sediments point to either a mechanism of recent salt removal, or to relatively modern permafrost soils (<1 million years). Together, our results show that near surface salts in University Valley serve as an end-member of stratospheric sources not subject to biological processes or extensive remobilization. (C) 2016 Elsevier Ltd. All rights reserved.


类型Article
语种英语
国家USA ; Canada ; Russia
收录类别SCI-E
WOS记录号WOS:000374503900012
WOS关键词MCMURDO DRY VALLEYS ; SOUTHERN-VICTORIA-LAND ; MIOCENE GLACIER ICE ; TAYLOR VALLEY ; ATMOSPHERIC NITRATE ; UNIVERSITY VALLEY ; BEACON-VALLEY ; GROUND ICE ; ANTARCTICA ; SOILS
WOS类目Geochemistry & Geophysics
WOS研究方向Geochemistry & Geophysics
来源机构United States Geological Survey
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/193166
作者单位1.Texas Tech Univ, Lubbock, TX 79409 USA;
2.SETI Inst, Carl Sagan Ctr, 189 Bernardo Ave, Mountain View, CA 94043 USA;
3.US Geol Survey, 431 Natl Ctr, Reston, VA 20192 USA;
4.Univ Delaware, Dept Geol Sci, Newark, DE 19716 USA;
5.Univ Ottawa, Dept Geog, Ottawa, ON K1N 6N5, Canada;
6.NASA, Ames Res Ctr, Moffett Field, CA 94035 USA;
7.Skolkovo Inst Sci & Technol, Moscow, Russia;
8.McGill Univ, Dept Geog, Montreal, PQ, Canada;
9.Honeybee Robot, 398 W Washington Blvd,Suite 200, Pasadena 91103, CA, Russia
推荐引用方式
GB/T 7714
Jackson, Andrew,Davila, Alfonso F.,Bohlke, John Karl,et al. Deposition, accumulation, and alteration of Cl-, NO3-, ClO4- and ClO3- salts in a hyper-arid polar environment: Mass balance and isotopic constraints[J]. United States Geological Survey,2016,182:197-215.
APA Jackson, Andrew.,Davila, Alfonso F..,Bohlke, John Karl.,Sturchio, Neil C..,Sevanthi, Ritesh.,...&Zacny, Kris.(2016).Deposition, accumulation, and alteration of Cl-, NO3-, ClO4- and ClO3- salts in a hyper-arid polar environment: Mass balance and isotopic constraints.GEOCHIMICA ET COSMOCHIMICA ACTA,182,197-215.
MLA Jackson, Andrew,et al."Deposition, accumulation, and alteration of Cl-, NO3-, ClO4- and ClO3- salts in a hyper-arid polar environment: Mass balance and isotopic constraints".GEOCHIMICA ET COSMOCHIMICA ACTA 182(2016):197-215.
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