Knowledge Resource Center for Ecological Environment in Arid Area
DOI | 10.5194/acp-16-14621-2016 |
Long-range atmospheric transport of volatile monocarboxylic acids with Asian dust over a high mountain snow site, central Japan | |
Mochizuki, Tomoki1,4; Kawamura, Kimitaka1,5; Aoki, Kazuma2; Sugimoto, Nobuo3 | |
通讯作者 | Kawamura, Kimitaka |
来源期刊 | ATMOSPHERIC CHEMISTRY AND PHYSICS
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ISSN | 1680-7316 |
EISSN | 1680-7324 |
出版年 | 2016 |
卷号 | 16期号:22页码:14621-14633 |
英文摘要 | To understand the long-range transport of monocarboxylic acids from the Asian continent to the Japanese islands, we collected snowpack samples from a pit sequence (depth ca. 6 m) at the Murodo-Daira snowfield near the summit of Mt. Tateyama, central Japan, in 2009 and 2011. Snow samples (n = 16) were analyzed for normal (C-1-C-10), branched chain (iC(4)-iC(6)), aromatic (benzoic and toluic acid isomers), and hydroxyl (glycolic and lactic) monocarboxylic acids, together with inorganic ions and dissolved organic carbon (DOC). Acetic acid (C2) was found to be a dominant species (average 125 ng g(-1)), followed by formic acid (C1)(85.7 ng g(-1)) and isopentanoic acid (iC(5))(20.0 ng g(-1)). We found a strong correlation (r=0.88) between formic plus acetic acids and non-sea-salt Ca2+ that is a proxy of Asian dust. Contributions of total monocarboxylic acids to DOC in 2009 (21.2 +/- 11.6 %) were higher than that in 2011 (3.75 +/- 2.62 %), being consistent with higher intensity of Asian dust in 2009 than in 2011. Formic plus acetic acids also showed a positive correlation (r=0.90) with benzoic acid that is a tracer of automobile exhaust, indicating that monocarboxylic acids and their precursors are largely emitted from anthropogenic sources in China and/or secondarily produced in the atmosphere by photochemical processing. In addition, the ratio of formic plus acetic acids to nss-Ca2+ (0.27) was significantly higher than those (0.00036-0.0018) obtained for reference dust materials of Chinese loess deposits from the Tengger and Gobi deserts. This result suggests that volatile and semi-volatile organic acids are adsorbed on the alkaline dust particles during long-range atmo-spheric transport. Entrainment of organic acids by dusts is supported by a good correlation (r=0.87) between formic plus acetic acids and pH of melt snow samples. Our study suggests that Asian alkaline dusts may be a carrier of volatile monocarboxylic acids. |
类型 | Article |
语种 | 英语 |
国家 | Japan |
收录类别 | SCI-E |
WOS记录号 | WOS:000388700000001 |
WOS关键词 | CARBOXYLIC-ACIDS ; CHEMICAL-COMPOSITION ; ORGANIC NITROGEN ; ACETIC-ACIDS ; AEROSOL ; PRECIPITATION ; ALDEHYDES ; SAMPLES ; CLOUDS ; GAS |
WOS类目 | Environmental Sciences ; Meteorology & Atmospheric Sciences |
WOS研究方向 | Environmental Sciences & Ecology ; Meteorology & Atmospheric Sciences |
资源类型 | 期刊论文 |
条目标识符 | http://119.78.100.177/qdio/handle/2XILL650/191584 |
作者单位 | 1.Hokkaido Univ, Inst Low Temp Sci, Kita Ku, N19 W8, Sapporo, Hokkaido 0600819, Japan; 2.Toyama Univ, Dept Earth Sci, Fac Sci, 3190 Gofuku, Toyama 9308555, Japan; 3.Natl Inst Environm Studies, 16-2 Onogawa, Tsukuba, Ibaraki 3058506, Japan; 4.Univ Shizuoka, Sch Food & Nutr Sci, 52-1 Yada, Shizuoka 4228526, Japan; 5.Chubu Univ, Chubu Inst Adv Studies, 1200 Matsumoto Cho, Kasugai, Aichi 4878501, Japan |
推荐引用方式 GB/T 7714 | Mochizuki, Tomoki,Kawamura, Kimitaka,Aoki, Kazuma,et al. Long-range atmospheric transport of volatile monocarboxylic acids with Asian dust over a high mountain snow site, central Japan[J],2016,16(22):14621-14633. |
APA | Mochizuki, Tomoki,Kawamura, Kimitaka,Aoki, Kazuma,&Sugimoto, Nobuo.(2016).Long-range atmospheric transport of volatile monocarboxylic acids with Asian dust over a high mountain snow site, central Japan.ATMOSPHERIC CHEMISTRY AND PHYSICS,16(22),14621-14633. |
MLA | Mochizuki, Tomoki,et al."Long-range atmospheric transport of volatile monocarboxylic acids with Asian dust over a high mountain snow site, central Japan".ATMOSPHERIC CHEMISTRY AND PHYSICS 16.22(2016):14621-14633. |
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