Arid
DOI10.5194/acp-16-14621-2016
Long-range atmospheric transport of volatile monocarboxylic acids with Asian dust over a high mountain snow site, central Japan
Mochizuki, Tomoki1,4; Kawamura, Kimitaka1,5; Aoki, Kazuma2; Sugimoto, Nobuo3
通讯作者Kawamura, Kimitaka
来源期刊ATMOSPHERIC CHEMISTRY AND PHYSICS
ISSN1680-7316
EISSN1680-7324
出版年2016
卷号16期号:22页码:14621-14633
英文摘要

To understand the long-range transport of monocarboxylic acids from the Asian continent to the Japanese islands, we collected snowpack samples from a pit sequence (depth ca. 6 m) at the Murodo-Daira snowfield near the summit of Mt. Tateyama, central Japan, in 2009 and 2011. Snow samples (n = 16) were analyzed for normal (C-1-C-10), branched chain (iC(4)-iC(6)), aromatic (benzoic and toluic acid isomers), and hydroxyl (glycolic and lactic) monocarboxylic acids, together with inorganic ions and dissolved organic carbon (DOC). Acetic acid (C2) was found to be a dominant species (average 125 ng g(-1)), followed by formic acid (C1)(85.7 ng g(-1)) and isopentanoic acid (iC(5))(20.0 ng g(-1)). We found a strong correlation (r=0.88) between formic plus acetic acids and non-sea-salt Ca2+ that is a proxy of Asian dust. Contributions of total monocarboxylic acids to DOC in 2009 (21.2 +/- 11.6 %) were higher than that in 2011 (3.75 +/- 2.62 %), being consistent with higher intensity of Asian dust in 2009 than in 2011. Formic plus acetic acids also showed a positive correlation (r=0.90) with benzoic acid that is a tracer of automobile exhaust, indicating that monocarboxylic acids and their precursors are largely emitted from anthropogenic sources in China and/or secondarily produced in the atmosphere by photochemical processing. In addition, the ratio of formic plus acetic acids to nss-Ca2+ (0.27) was significantly higher than those (0.00036-0.0018) obtained for reference dust materials of Chinese loess deposits from the Tengger and Gobi deserts. This result suggests that volatile and semi-volatile organic acids are adsorbed on the alkaline dust particles during long-range atmo-spheric transport. Entrainment of organic acids by dusts is supported by a good correlation (r=0.87) between formic plus acetic acids and pH of melt snow samples. Our study suggests that Asian alkaline dusts may be a carrier of volatile monocarboxylic acids.


类型Article
语种英语
国家Japan
收录类别SCI-E
WOS记录号WOS:000388700000001
WOS关键词CARBOXYLIC-ACIDS ; CHEMICAL-COMPOSITION ; ORGANIC NITROGEN ; ACETIC-ACIDS ; AEROSOL ; PRECIPITATION ; ALDEHYDES ; SAMPLES ; CLOUDS ; GAS
WOS类目Environmental Sciences ; Meteorology & Atmospheric Sciences
WOS研究方向Environmental Sciences & Ecology ; Meteorology & Atmospheric Sciences
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/191584
作者单位1.Hokkaido Univ, Inst Low Temp Sci, Kita Ku, N19 W8, Sapporo, Hokkaido 0600819, Japan;
2.Toyama Univ, Dept Earth Sci, Fac Sci, 3190 Gofuku, Toyama 9308555, Japan;
3.Natl Inst Environm Studies, 16-2 Onogawa, Tsukuba, Ibaraki 3058506, Japan;
4.Univ Shizuoka, Sch Food & Nutr Sci, 52-1 Yada, Shizuoka 4228526, Japan;
5.Chubu Univ, Chubu Inst Adv Studies, 1200 Matsumoto Cho, Kasugai, Aichi 4878501, Japan
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Mochizuki, Tomoki,Kawamura, Kimitaka,Aoki, Kazuma,et al. Long-range atmospheric transport of volatile monocarboxylic acids with Asian dust over a high mountain snow site, central Japan[J],2016,16(22):14621-14633.
APA Mochizuki, Tomoki,Kawamura, Kimitaka,Aoki, Kazuma,&Sugimoto, Nobuo.(2016).Long-range atmospheric transport of volatile monocarboxylic acids with Asian dust over a high mountain snow site, central Japan.ATMOSPHERIC CHEMISTRY AND PHYSICS,16(22),14621-14633.
MLA Mochizuki, Tomoki,et al."Long-range atmospheric transport of volatile monocarboxylic acids with Asian dust over a high mountain snow site, central Japan".ATMOSPHERIC CHEMISTRY AND PHYSICS 16.22(2016):14621-14633.
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