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DOI10.1016/j.saa.2015.06.051
Raman spectroscopic study of the Chromobacterium violaceum pigment violacein using multiwavelength excitation and DFT calculations
Jehlicka, Jan1; Edwards, Howell G. M.2; Nemec, Ivan3; Oren, Aharon4
通讯作者Jehlicka, Jan
来源期刊SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
ISSN1386-1425
出版年2015
卷号151页码:459-467
英文摘要

Violacein is a bisindole pigment occurring as a biosynthetic product of Chromobacterium violaceum and Janthinobacterium lividum. It has some structural similarities to the cyanobacterial UV-protective pigment scytonemin, which has been the subject of comprehensive spectroscopic and structural studies. A detailed experimental Raman spectroscopic study with visible and near-infrared excitation of violacein produced by C. violaceum has been undertaken and supported using theoretical DFT calculations. Raman spectra with 514 and 785 nm excitation of cultivated cells as well as extracts and Gaussian (B3LY13/6-311++G(d,p)) calculations with proposed molecular vibrational assignments are reported here. (C) 2015 Elsevier B.V. All rights reserved.


英文关键词Raman spectroscopy UV protective pigment Cyanobacteria DFT calculations
类型Article
语种英语
国家Czech Republic ; England ; Israel
收录类别SCI-E
WOS记录号WOS:000361861300059
WOS关键词ATACAMA DESERT ; BIOSYNTHETIC-PATHWAY ; CAROTENOIDS ; SPECTRA ; SCYTONEMIN ; RELEVANCE ; BACTERIA ; POLYENES ; HALITE
WOS类目Spectroscopy
WOS研究方向Spectroscopy
来源机构Hebrew University of Jerusalem
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/190546
作者单位1.Charles Univ Prague, Inst Geochem Mineral & Mineral Resources, Prague 12843, Czech Republic;
2.Univ Bradford, Sch Life Sci, Ctr Astrobiol & Extremophiles Res, Bradford BD7 1DP, W Yorkshire, England;
3.Charles Univ Prague, Dept Inorgan Chem, CR-12840 Prague, Czech Republic;
4.Hebrew Univ Jerusalem, Dept Plant & Environm Sci, Inst Life Sci, IL-91904 Jerusalem, Israel
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Jehlicka, Jan,Edwards, Howell G. M.,Nemec, Ivan,et al. Raman spectroscopic study of the Chromobacterium violaceum pigment violacein using multiwavelength excitation and DFT calculations[J]. Hebrew University of Jerusalem,2015,151:459-467.
APA Jehlicka, Jan,Edwards, Howell G. M.,Nemec, Ivan,&Oren, Aharon.(2015).Raman spectroscopic study of the Chromobacterium violaceum pigment violacein using multiwavelength excitation and DFT calculations.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,151,459-467.
MLA Jehlicka, Jan,et al."Raman spectroscopic study of the Chromobacterium violaceum pigment violacein using multiwavelength excitation and DFT calculations".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 151(2015):459-467.
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