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DOI | 10.1016/j.saa.2015.06.051 |
Raman spectroscopic study of the Chromobacterium violaceum pigment violacein using multiwavelength excitation and DFT calculations | |
Jehlicka, Jan1; Edwards, Howell G. M.2; Nemec, Ivan3; Oren, Aharon4 | |
通讯作者 | Jehlicka, Jan |
来源期刊 | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
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ISSN | 1386-1425 |
出版年 | 2015 |
卷号 | 151页码:459-467 |
英文摘要 | Violacein is a bisindole pigment occurring as a biosynthetic product of Chromobacterium violaceum and Janthinobacterium lividum. It has some structural similarities to the cyanobacterial UV-protective pigment scytonemin, which has been the subject of comprehensive spectroscopic and structural studies. A detailed experimental Raman spectroscopic study with visible and near-infrared excitation of violacein produced by C. violaceum has been undertaken and supported using theoretical DFT calculations. Raman spectra with 514 and 785 nm excitation of cultivated cells as well as extracts and Gaussian (B3LY13/6-311++G(d,p)) calculations with proposed molecular vibrational assignments are reported here. (C) 2015 Elsevier B.V. All rights reserved. |
英文关键词 | Raman spectroscopy UV protective pigment Cyanobacteria DFT calculations |
类型 | Article |
语种 | 英语 |
国家 | Czech Republic ; England ; Israel |
收录类别 | SCI-E |
WOS记录号 | WOS:000361861300059 |
WOS关键词 | ATACAMA DESERT ; BIOSYNTHETIC-PATHWAY ; CAROTENOIDS ; SPECTRA ; SCYTONEMIN ; RELEVANCE ; BACTERIA ; POLYENES ; HALITE |
WOS类目 | Spectroscopy |
WOS研究方向 | Spectroscopy |
来源机构 | Hebrew University of Jerusalem |
资源类型 | 期刊论文 |
条目标识符 | http://119.78.100.177/qdio/handle/2XILL650/190546 |
作者单位 | 1.Charles Univ Prague, Inst Geochem Mineral & Mineral Resources, Prague 12843, Czech Republic; 2.Univ Bradford, Sch Life Sci, Ctr Astrobiol & Extremophiles Res, Bradford BD7 1DP, W Yorkshire, England; 3.Charles Univ Prague, Dept Inorgan Chem, CR-12840 Prague, Czech Republic; 4.Hebrew Univ Jerusalem, Dept Plant & Environm Sci, Inst Life Sci, IL-91904 Jerusalem, Israel |
推荐引用方式 GB/T 7714 | Jehlicka, Jan,Edwards, Howell G. M.,Nemec, Ivan,et al. Raman spectroscopic study of the Chromobacterium violaceum pigment violacein using multiwavelength excitation and DFT calculations[J]. Hebrew University of Jerusalem,2015,151:459-467. |
APA | Jehlicka, Jan,Edwards, Howell G. M.,Nemec, Ivan,&Oren, Aharon.(2015).Raman spectroscopic study of the Chromobacterium violaceum pigment violacein using multiwavelength excitation and DFT calculations.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,151,459-467. |
MLA | Jehlicka, Jan,et al."Raman spectroscopic study of the Chromobacterium violaceum pigment violacein using multiwavelength excitation and DFT calculations".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 151(2015):459-467. |
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