Arid
DOI10.1016/j.nimb.2015.09.008
PIXE micro-mapping of minor elements in Hypatia, a diamond bearing carbonaceous stone from the Libyan Desert Glass area, Egypt: Inheritance from a cold molecular cloud?
Andreoli, M. A. G.1; Przybylowicz, W. J.2,3; Kramers, J.4; Belyanin, G.4; Westraadt, J.5; Bamford, M.6; Mesjasz-Przybylowicz, J.2; Venter, A.7
通讯作者Andreoli, M. A. G.
来源期刊NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
ISSN0168-583X
EISSN1872-9584
出版年2015
卷号363页码:79-85
英文摘要

Matter originating from space, particularly if it represents rare meteorite samples, is ideally suited to be studied by Particle Induced X-ray Emission (PIXE) as this analytical technique covers a broad range of trace elements and is per se non-destructive. We describe and interpret a set of micro-PIXE elemental maps obtained on two minute (weighing about 25 and 150 mg), highly polished fragments taken from Hypatia, a controversial, diamond-bearing carbonaceous pebble from the SW Egyptian desert. PIXE data show that Hypatia is chemically heterogeneous, with significant amounts of primordial S, CI, P and at least 10 elements with Z >21 (Ti, V, Cr, Mn, Fe, Ni, Os, Ir) locally attaining concentrations above 500 ppm. Si, Al, Ca, K, O also occur, but are predominantly confined to cracks and likely represent contamination from the desert environment. Unusual in the stone is poor correlation between elements within the chalcophile (S vs. Cu, Zn) and siderophile (i.e.: Fe vs. Ni, Ir, Os) groups, whereas other siderophiles (Mn, Mo and the Platinum group elements (PGEs)) mimic the distribution of lithophile elements such as Cr and V. Worthy of mention is also the presence of a globular domain (empty set similar to 120 mu m) that is C and metals-depleted, yet Cl (P)-enriched (>3 wt.% and 0.15 wt.% respectively). While the host of the Cl remains undetermined, this chemical unit is enclosed within a broader domain that is similarly C-poor, yet Cr-Ir rich (up to 1.2 and 0.3 wt.% respectively). Our data suggest that the pebble consists of shock-compacted, primitive carbonaceous material enriched in cold, pre-solar dust. (C) 2015 Elsevier B.V. All rights reserved.


英文关键词Hypatia Pre-solar dust Micro-PIXE Dynamic Analysis
类型Article
语种英语
国家South Africa ; Poland
收录类别SCI-E
WOS记录号WOS:000366079500015
WOS关键词MICROANALYSIS
WOS类目Instruments & Instrumentation ; Nuclear Science & Technology ; Physics, Atomic, Molecular & Chemical ; Physics, Nuclear
WOS研究方向Instruments & Instrumentation ; Nuclear Science & Technology ; Physics
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/189384
作者单位1.Univ Witwatersrand, Sch Geosci, ZA-2050 Johannesburg, South Africa;
2.Natl Res Fdn, iThemba LABS, ZA-7129 Somerset West, South Africa;
3.AGH Univ Sci & Technol, Fac Phys & Appl Comp Sci, PL-30059 Krakow, Poland;
4.Univ Johannesburg, Dept Geol, ZA-2006 Auckland Pk, South Africa;
5.Nelson Mandela Metropolitan Univ, Dept Phys, ZA-6031 Port Elizabeth, South Africa;
6.Univ Witwatersrand, Evolutionary Studies Inst, ZA-2050 Johannesburg, South Africa;
7.South African Nucl Energy Corp, ZA-0001 Pretoria, South Africa
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Andreoli, M. A. G.,Przybylowicz, W. J.,Kramers, J.,et al. PIXE micro-mapping of minor elements in Hypatia, a diamond bearing carbonaceous stone from the Libyan Desert Glass area, Egypt: Inheritance from a cold molecular cloud?[J],2015,363:79-85.
APA Andreoli, M. A. G..,Przybylowicz, W. J..,Kramers, J..,Belyanin, G..,Westraadt, J..,...&Venter, A..(2015).PIXE micro-mapping of minor elements in Hypatia, a diamond bearing carbonaceous stone from the Libyan Desert Glass area, Egypt: Inheritance from a cold molecular cloud?.NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS,363,79-85.
MLA Andreoli, M. A. G.,et al."PIXE micro-mapping of minor elements in Hypatia, a diamond bearing carbonaceous stone from the Libyan Desert Glass area, Egypt: Inheritance from a cold molecular cloud?".NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS 363(2015):79-85.
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