Arid
DOI10.1111/maps.12384
Siderophile and chalcophile element abundances in shergottites: Implications for Martian core formation
Yang, Shuying1,2; Humayun, Munir1,2; Righter, Kevin3; Jefferson, Gwendolyn1,4; Fields, Dana1,5; Irving, Anthony J.6
通讯作者Humayun, Munir
来源期刊METEORITICS & PLANETARY SCIENCE
ISSN1086-9379
EISSN1945-5100
出版年2015
卷号50期号:4页码:691-714
英文摘要

Elemental abundances for volatile siderophile and chalcophile elements for Mars inform us about processes of accretion and core formation. Such data are few for Martian meteorites, and are often lacking in the growing number of desert finds. In this study, we employed laser ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) to analyze polished slabs of 15 Martian meteorites for the abundances of about 70 elements. This technique has high sensitivity, excellent precision, and is generally accurate as determined by comparisons of elements for which literature abundances are known. However, in some meteorites, the analyzed surface is not representative of the bulk composition due to the over- or underrepresentation of a key host mineral, e.g., phosphate for rare earth elements (REE). For other meteorites, the range of variation in bulk rastered analyses of REE is within the range of variation reported among bulk REE analyses in the literature. An unexpected benefit has been the determination of the abundances of Ir and Os with a precision and accuracy comparable to the isotope dilution technique. Overall, the speed and small sample consumption afforded by this technique makes it an important tool widely applicable to small or rare meteorites for which a polished sample was prepared. The new volatile siderophile and chalcophile element abundances have been employed to determine Ge and Sb abundances, and revise Zn, As, and Bi abundances for the Martian mantle. The new estimates of Martian mantle composition support core formation at intermediate pressures (14 +/- 3GPa) in a magma ocean on Mars.


类型Article
语种英语
国家USA
收录类别SCI-E
WOS记录号WOS:000352625200012
WOS关键词TRACE-ELEMENTS ; SILICATE MELT ; CHEMICAL-COMPOSITION ; PLANETARY CORES ; OXYGEN FUGACITY ; METAL ; EARTH ; MANTLE ; CONSTRAINTS ; METEORITE
WOS类目Geochemistry & Geophysics
WOS研究方向Geochemistry & Geophysics
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/189191
作者单位1.Florida State Univ, Natl High Magnet Field Lab, Tallahassee, FL 32310 USA;
2.Florida State Univ, Dept Earth Ocean & Atmospher Sci, Tallahassee, FL 32310 USA;
3.NASA, Lyndon B Johnson Space Ctr, Mailcode KT, Houston, TX 77058 USA;
4.Carter High Sch, Rialto, CA 92376 USA;
5.Rickards High Sch, Tallahassee, FL 32306 USA;
6.Univ Washington, Dept Earth & Space Sci, Seattle, WA 98195 USA
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Yang, Shuying,Humayun, Munir,Righter, Kevin,et al. Siderophile and chalcophile element abundances in shergottites: Implications for Martian core formation[J],2015,50(4):691-714.
APA Yang, Shuying,Humayun, Munir,Righter, Kevin,Jefferson, Gwendolyn,Fields, Dana,&Irving, Anthony J..(2015).Siderophile and chalcophile element abundances in shergottites: Implications for Martian core formation.METEORITICS & PLANETARY SCIENCE,50(4),691-714.
MLA Yang, Shuying,et al."Siderophile and chalcophile element abundances in shergottites: Implications for Martian core formation".METEORITICS & PLANETARY SCIENCE 50.4(2015):691-714.
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