干旱区生态环境知识资源中心

In this study, we introduce a method for large-area and substrate-independent synthesis of the big-inner-diameter carbon nanotube (BIDI-CNT) thin films by utilizing polydopamine (PDA) as carbon source and ZnO nanorods (NRs) as sacrificing template for the first time. ZnO NRs with hexagonal morphology were coated with FDA films via the ammonium persulfate-induced polymerization of dopamine at neutral pH for avoiding the degradation of amphoteric ZnO at alkaline pH needed by the conventional oxygen-induced polymerization of dopamine. After carbonization in N-2 atmosphere at 500 degrees C followed by ZnO removal, the hollow BIDI-CNTs with tuned wall thickness and hexagonal morphology were obtained. In addition, the obtained BIDI-CNTs were found to be N-doped. Furthermore, on the base of the outstanding substrate-independent growth properties of both ZnO NRs arid FDA, the large area thin films of the N-doped BIDI-CNTs could be synthesized on various solid substrates, for instance, Al2O3, gold, fluorine-doped tin oxide-coated glass, platinum, silicon, mica, and quartz. (C) 2014 Elsevier Ltd. All rights reserved.