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There is increasing need to characterize the distribution of snow in complex terrain using remote sensing approaches, especially in isolated mountainous regions that are often water-limited, the principal source of terrestrial freshwater, and sensitive to climatic shifts and variations. We apply intensive topographic surveys, multi-temporal LiDAR, and Random Forest modeling to quantify snow volume and characterize associated errors across seven land cover types in a semi-arid mountainous catchment at a 1 and 4 m spatial resolution. The LiDAR-based estimates of both snow-off surface topology and snow depths were validated against ground-based measurements across the catchment. LiDAR-derived snow depths estimates were most accurate in areas of low lying vegetation such as meadow and shrub vegetation (RMSE = 0.14 m) as compared to areas consisting of tree cover (RMSE = 0.20-0.35 m). The highest errors were found along the edge of conifer forests (RMSE = 0.35 m), however a second conifer transect outside the catchment had much lower errors (RMSE = 0.21 m). This difference is attributed to the wind exposure of the first site that led to highly variable snow depths at short spatial distances. The Random Forest modeled errors deviated from the field measured errors with-a RMSE of 0.09-0.34 m across the different cover types. The modeling was used to calculate a theoretical lower and upper bound of catchment snow volume error of 21-30%. Results show that snow drifts, which are important for maintaining spring and summer stream flows and establishing and sustaining water-limited plant species, contained 30 +/- 5-6% of the snow volume while only occupying 10% of the catchment area similar to findings by prior physically-based modeling approaches. This study demonstrates the potential utility of combining multi-temporal LiDAR with Random Forest modeling to quantify the distribution of snow depth with a reasonable degree of accuracy. (C) 2013 Elsevier Inc. All rights reserved.