Arid
DOI10.1016/j.gca.2014.07.031
Examination of Cr(VI) treatment by zero-valent iron using in situ, real-time X-ray absorption spectroscopy and Cr isotope measurements
Jamieson-Hanes, Julia H.; Lentz, Adam M.; Amos, Richard T.; Ptacek, Carol J.; Blowes, David W.
通讯作者Blowes, David W.
来源期刊GEOCHIMICA ET COSMOCHIMICA ACTA
ISSN0016-7037
EISSN1872-9533
出版年2014
卷号142页码:299-313
英文摘要

A series of replicate flow-through cell experiments was conducted to characterize Cr isotope fractionation during Cr(VI) treatment by granular zero-valent iron (ZVI). Synthetic groundwater containing 50 mg L-1 Cr(VI) was pumped upward through a custom-made cell packed with ZVI under anaerobic conditions. The geochemical evolution of the system was monitored using pH and redox measurements, while aqueous effluent samples were retained for analysis of cations and Cr isotopes. Real-time, in situ X-ray absorption near edge structure (XANES) spectroscopy collected via a Kapton (R) window in the cell provided additional information on the speciation of the reaction products. Increases in d 53 Cr values corresponding to decreases in Cr(VI) concentration suggested the occurrence of redox processes. Spectroscopic results correlated well with the isotope data, indicating reduction of Cr(VI) to Cr(III). The isotope data did not appear to follow a single trend. A two-stage system was proposed to explain the complex isotope trend, where the rapid Cr removal was associated with very little fractionation (epsilon = -0.2 parts per thousand), whereas slower removal was associated with a greater degree of fractionation (epsilon = -1.2 parts per thousand to -1.5 parts per thousand). Reactive transport modeling was used to quantify distinct isotope fractionation values (epsilon), differentiated by a significant change in the Cr removal rate. (C) 2014 Elsevier Ltd. All rights reserved.


类型Article
语种英语
国家Canada
收录类别SCI-E
WOS记录号WOS:000342622400020
WOS关键词HEXAVALENT CHROMIUM REDUCTION ; REACTIVE BARRIER ; GRANULAR IRON ; STABLE-ISOTOPES ; CONTAMINATED GROUNDWATER ; FRACTIONATION FACTORS ; DISSOLVED CACO3 ; MOJAVE DESERT ; TRANSPORT ; CHROMATE
WOS类目Geochemistry & Geophysics
WOS研究方向Geochemistry & Geophysics
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/182225
作者单位Univ Waterloo, Dept Earth & Environm Sci, Waterloo, ON N2L 3G1, Canada
推荐引用方式
GB/T 7714
Jamieson-Hanes, Julia H.,Lentz, Adam M.,Amos, Richard T.,et al. Examination of Cr(VI) treatment by zero-valent iron using in situ, real-time X-ray absorption spectroscopy and Cr isotope measurements[J],2014,142:299-313.
APA Jamieson-Hanes, Julia H.,Lentz, Adam M.,Amos, Richard T.,Ptacek, Carol J.,&Blowes, David W..(2014).Examination of Cr(VI) treatment by zero-valent iron using in situ, real-time X-ray absorption spectroscopy and Cr isotope measurements.GEOCHIMICA ET COSMOCHIMICA ACTA,142,299-313.
MLA Jamieson-Hanes, Julia H.,et al."Examination of Cr(VI) treatment by zero-valent iron using in situ, real-time X-ray absorption spectroscopy and Cr isotope measurements".GEOCHIMICA ET COSMOCHIMICA ACTA 142(2014):299-313.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Jamieson-Hanes, Julia H.]的文章
[Lentz, Adam M.]的文章
[Amos, Richard T.]的文章
百度学术
百度学术中相似的文章
[Jamieson-Hanes, Julia H.]的文章
[Lentz, Adam M.]的文章
[Amos, Richard T.]的文章
必应学术
必应学术中相似的文章
[Jamieson-Hanes, Julia H.]的文章
[Lentz, Adam M.]的文章
[Amos, Richard T.]的文章
相关权益政策
暂无数据
收藏/分享

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。