Knowledge Resource Center for Ecological Environment in Arid Area
DOI | 10.1016/j.gca.2014.07.031 |
Examination of Cr(VI) treatment by zero-valent iron using in situ, real-time X-ray absorption spectroscopy and Cr isotope measurements | |
Jamieson-Hanes, Julia H.; Lentz, Adam M.; Amos, Richard T.; Ptacek, Carol J.; Blowes, David W. | |
通讯作者 | Blowes, David W. |
来源期刊 | GEOCHIMICA ET COSMOCHIMICA ACTA
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ISSN | 0016-7037 |
EISSN | 1872-9533 |
出版年 | 2014 |
卷号 | 142页码:299-313 |
英文摘要 | A series of replicate flow-through cell experiments was conducted to characterize Cr isotope fractionation during Cr(VI) treatment by granular zero-valent iron (ZVI). Synthetic groundwater containing 50 mg L-1 Cr(VI) was pumped upward through a custom-made cell packed with ZVI under anaerobic conditions. The geochemical evolution of the system was monitored using pH and redox measurements, while aqueous effluent samples were retained for analysis of cations and Cr isotopes. Real-time, in situ X-ray absorption near edge structure (XANES) spectroscopy collected via a Kapton (R) window in the cell provided additional information on the speciation of the reaction products. Increases in d 53 Cr values corresponding to decreases in Cr(VI) concentration suggested the occurrence of redox processes. Spectroscopic results correlated well with the isotope data, indicating reduction of Cr(VI) to Cr(III). The isotope data did not appear to follow a single trend. A two-stage system was proposed to explain the complex isotope trend, where the rapid Cr removal was associated with very little fractionation (epsilon = -0.2 parts per thousand), whereas slower removal was associated with a greater degree of fractionation (epsilon = -1.2 parts per thousand to -1.5 parts per thousand). Reactive transport modeling was used to quantify distinct isotope fractionation values (epsilon), differentiated by a significant change in the Cr removal rate. (C) 2014 Elsevier Ltd. All rights reserved. |
类型 | Article |
语种 | 英语 |
国家 | Canada |
收录类别 | SCI-E |
WOS记录号 | WOS:000342622400020 |
WOS关键词 | HEXAVALENT CHROMIUM REDUCTION ; REACTIVE BARRIER ; GRANULAR IRON ; STABLE-ISOTOPES ; CONTAMINATED GROUNDWATER ; FRACTIONATION FACTORS ; DISSOLVED CACO3 ; MOJAVE DESERT ; TRANSPORT ; CHROMATE |
WOS类目 | Geochemistry & Geophysics |
WOS研究方向 | Geochemistry & Geophysics |
资源类型 | 期刊论文 |
条目标识符 | http://119.78.100.177/qdio/handle/2XILL650/182225 |
作者单位 | Univ Waterloo, Dept Earth & Environm Sci, Waterloo, ON N2L 3G1, Canada |
推荐引用方式 GB/T 7714 | Jamieson-Hanes, Julia H.,Lentz, Adam M.,Amos, Richard T.,et al. Examination of Cr(VI) treatment by zero-valent iron using in situ, real-time X-ray absorption spectroscopy and Cr isotope measurements[J],2014,142:299-313. |
APA | Jamieson-Hanes, Julia H.,Lentz, Adam M.,Amos, Richard T.,Ptacek, Carol J.,&Blowes, David W..(2014).Examination of Cr(VI) treatment by zero-valent iron using in situ, real-time X-ray absorption spectroscopy and Cr isotope measurements.GEOCHIMICA ET COSMOCHIMICA ACTA,142,299-313. |
MLA | Jamieson-Hanes, Julia H.,et al."Examination of Cr(VI) treatment by zero-valent iron using in situ, real-time X-ray absorption spectroscopy and Cr isotope measurements".GEOCHIMICA ET COSMOCHIMICA ACTA 142(2014):299-313. |
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