Arid
DOI10.2134/jeq2013.04.0138
Sorption/Desorption of Lincomycin from Three Arid-Region Soils
Williams, C. F.1; Watson, J. E.2; Nelson, S. D.3; Walker, C. W.4
通讯作者Williams, C. F.
来源期刊JOURNAL OF ENVIRONMENTAL QUALITY
ISSN0047-2425
出版年2013
卷号42期号:5页码:1460-1465
英文摘要

The antibiotic lincomycin is commonly found in treated municipal waste water and in waste from swine and poultry production. Environmental disposal of these wastes has the potential to introduce a significant mass of lincomycin into the ecosystem. In the present study, a series of sorption and desorption experiments were conducted to determine the potential mobility of lincomycin in soils from arid environments. Sorption and desorption isotherms were obtained for lincomycin using three different soils. Isotherms were fit to the Freundlich equation. Adsorption of lincomycin was found to have a K-f of 11.98 for a biosolid-treated soil (1.58% OC) and a K-f of 210.15 for a similar unamended soil (1.42% OC). It was also found that for a low-organic-content soil the K-f was 5.09. The differences in adsorption can be related to the soil pH and the pKa of lincomycin (7.5-7.8). When the soil solution pH is below the pKa, the cationic species of lincomycin dominates, resulting in increased water solubility. Interaction with the cation exchange complex is minimal due to a high solution cation concentration (Ca2+ and Na+). Desorption isotherms also indicate that when the solution pH is lower than the pKa, retention of lincomycin is reduced. Our results indicate that the mobility of lincomycin in these arid region soils is dependent on soil pH.


类型Article
语种英语
国家USA
收录类别SCI-E
WOS记录号WOS:000324095200016
WOS关键词DISSOLVED ORGANIC-MATTER ; WASTE-WATER TREATMENT ; LIQUID SWINE MANURE ; VETERINARY ANTIBIOTICS ; ENVIRONMENT ; FATE ; COMPLEXATION ; CLINDAMYCIN ; RESIDUES ; REMOVAL
WOS类目Environmental Sciences
WOS研究方向Environmental Sciences & Ecology
来源机构United States Geological Survey
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/178292
作者单位1.USDA ARS, US Arid Land Agr Res Ctr, Maricopa, AZ 85138 USA;
2.Penn State Univ, Crop & Soil Sci Dep, University Pk, PA 16802 USA;
3.Texas A&M Univ, Dep Agron & Resource Sci, Kingsville, TX 78363 USA;
4.US Geol Survey, MD DE DC Water Sci Ctr, Catonsville, MD 21228 USA
推荐引用方式
GB/T 7714
Williams, C. F.,Watson, J. E.,Nelson, S. D.,et al. Sorption/Desorption of Lincomycin from Three Arid-Region Soils[J]. United States Geological Survey,2013,42(5):1460-1465.
APA Williams, C. F.,Watson, J. E.,Nelson, S. D.,&Walker, C. W..(2013).Sorption/Desorption of Lincomycin from Three Arid-Region Soils.JOURNAL OF ENVIRONMENTAL QUALITY,42(5),1460-1465.
MLA Williams, C. F.,et al."Sorption/Desorption of Lincomycin from Three Arid-Region Soils".JOURNAL OF ENVIRONMENTAL QUALITY 42.5(2013):1460-1465.
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