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A new methodology to derive the spatial distribution of clay pans from satellite microwave data is presented. Soil moisture has a different temporal signature in clay pans compared with other soils, which is directly reflected in the satellite-observed brightness temperatures. Three years of Advanced Microwave Scanning Radiometer Earth Observing System (AMSR-E) 6.9GHz microwave observations were compiled and analysed over continental Australia to identify clay pans. This led to the development of a brightness temperature variance index (BTVI), which shows a strong spatial correspondence to an existing soil texture map and the ability to map clay pans for semi-arid regions. This simple method emphasizes the potential use of passive microwave remote sensing for soil type mapping.