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The Namaqualand area is located in the Northern Cape Province of South Africa which is characterised by arid climate where groundwater is the only source of water supply for local communities. Extensive groundwater sampling was carried out in the area and the physico-chemical parameters, inorganic constituents, stable isotopes and trace metals were measured. The hydrochemistry of the area indicates dissimilar groundwater composition due to complex geochemical processes where groundwater flow takes place from catchment F30A to the catchment D82B, and the chemistry is controlled primarily by Redox reaction, dissolution and mixing processes. The Br-/Cl- ratio revealed that the salinity in the area is derived from seawater mixing, halite dissolution and atmospheric deposition/sea aerosol spray. Under excessive evaporative condition due to climatic aridity, groundwater salinity shows increasing trend. Isotope results show the presence of shallow-weathered zone and deep-fracture controlled circulating groundwater in the crystalline basement aquifer of the area. In comparison to the South African water quality standard, the results obtained for gross alpha activity which could be derived from uranium isotopes show that 41 % of the reported data in the area fall above the drinking water limit.