Arid
DOI10.1111/maps.12015
Metal-saturated sulfide assemblages in NWA 2737: Evidence for impact-related sulfur devolatilization in Martian meteorites
Lorand, Jean-Pierre1,2; Barrat, Jean-Alix3; Chevrier, Vincent4; Sautter, Violaine5; Pont, Sylvain5
通讯作者Lorand, Jean-Pierre
来源期刊METEORITICS & PLANETARY SCIENCE
ISSN1086-9379
EISSN1945-5100
出版年2012
卷号47期号:11页码:1830-1841
英文摘要

NWA 2737, a Martian meteorite from the Chassignite subclass, contains minute amounts (0.010 +/- 0.005 vol%) of metal-saturated Fe-Ni sulfides. These latter bear evidence of the strong shock effects documented by abundant Fe nanoparticles and planar defects in Northwest Africa (NWA) 2737 olivine. A Ni-poor troilite (Fe/S = 1.0 +/- 0.01), sometimes Cr-bearing (up to 1 wt%), coexists with micrometer-sized taenite/tetrataenite-type native NiFe alloys (Ni/Fe = 1) and Fe-Os-Ir-(Ru) alloys a few hundreds of nanometers across. The troilite has exsolved flame-like pentlandite (Fe/Fe + Ni = 0.5-0.6). Chalcopyrite is almost lacking, and no pyrite has been found. As a hot desert find, NWA 2737 shows astonishingly fresh sulfides. The composition of troilite coexisting with Ni-Fe alloys is completely at odds with Chassigny and Nahkla sulfides (pyrite + metal-deficient monoclinic-type pyrrhotite). It indicates strongly reducing crystallization conditions (close to IW), several log units below the fO(2) conditions inferred from chromites compositions and accepted for Chassignites (FMQ-1 log unit). It is proposed that reduction in sulfides into base and precious metal alloys is operated via sulfur degassing, which is supported by the highly resorbed and denticulated shape of sulfide blebs and their spongy textures. Shock-related S degassing may be responsible for considerable damages in magmatic sulfide structures and sulfide assemblages, with concomitant loss of magnetic properties as documented in some other Martian meteorites.


类型Article
语种英语
国家France ; USA
收录类别SCI-E
WOS记录号WOS:000313985100010
WOS关键词MONOSULFIDE SOLID-SOLUTION ; PLATINUM-GROUP ELEMENTS ; NI-CU SULFIDES ; SHOCK METAMORPHISM ; MAGNETIC-PROPERTIES ; HIGH-TEMPERATURE ; OXYGEN FUGACITY ; SNC METEORITES ; UPPER-MANTLE ; FE
WOS类目Geochemistry & Geophysics
WOS研究方向Geochemistry & Geophysics
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/174053
作者单位1.Univ Nantes, Lab Planetol & Geodynam Nantes, F-44322 Nantes 3, France;
2.Ctr Natl Rech Sci UMR 6112, F-44322 Nantes 3, France;
3.Univ Bretagne Occidentale, Inst Univ Europeen Mer, F-29280 Plouzane, France;
4.Univ Arkansas, WM Keck Lab Space & Planetary Simulat, Arkansas Ctr Space & Planetary Sci, Fayetteville, AR 72701 USA;
5.Museum Natl Hist Nat, Lab Mineral & Cosmochim, CNRS UMR 7202, F-75005 Paris, France
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GB/T 7714
Lorand, Jean-Pierre,Barrat, Jean-Alix,Chevrier, Vincent,et al. Metal-saturated sulfide assemblages in NWA 2737: Evidence for impact-related sulfur devolatilization in Martian meteorites[J],2012,47(11):1830-1841.
APA Lorand, Jean-Pierre,Barrat, Jean-Alix,Chevrier, Vincent,Sautter, Violaine,&Pont, Sylvain.(2012).Metal-saturated sulfide assemblages in NWA 2737: Evidence for impact-related sulfur devolatilization in Martian meteorites.METEORITICS & PLANETARY SCIENCE,47(11),1830-1841.
MLA Lorand, Jean-Pierre,et al."Metal-saturated sulfide assemblages in NWA 2737: Evidence for impact-related sulfur devolatilization in Martian meteorites".METEORITICS & PLANETARY SCIENCE 47.11(2012):1830-1841.
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