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The morphometric analysis of river basins represents a simple procedure to describe hydrologic and geomorphic processes operating on a basin scale. A morphometric analysis was carried out to evaluate the drainage characteristics of two adjoining, mountain river basins of the southern Western Ghats, India, Muthirapuzha River Basin (MRB) in the western slopes and Pambar River Basin (PRB) in the eastern slopes. The basins, forming a part of the Proterozoic, high-grade, Southern Granulite Terrain of the Peninsular India, are carved out of a terrain dominantly made of granite- and hornblende-biotite gneisses. The Western Ghats, forming the basin divide, significantly influences the regional climate (i.e., humid climate in MRB, while semi-arid in PRB). The Survey of India topographic maps (1:50,000) and Shuttle Radar Topographic Mission digital elevation data were used as the base for delineation and analysis. Both river basins are of 6th order and comparable in basin geometry. The drainage patterns and linear alignment of the drainage networks suggest the influence of structural elements. The Rb of either basins failed to highlight the structural controls on drainage organization, which might be a result of the elongated basin shape. The irregular trends in Rb between various stream orders suggest the influence of geology and relief on drainage branching. The Dd values designate the basins as moderate- to well-drained with lower infiltration rates. The overall increasing trend of Rl between successive stream orders suggests a geomorphic maturity of either basins and confirmed by the characteristic I (hyp) values. The Re values imply an elongate shape for both MRB and PRB and subsequently lower vulnerability to flash floods and hence, easier flood management. The relatively higher Rr of PRB is an indicative of comparatively steeply sloping terrain and consequently higher intensity of erosion processes. Further, the derivatives of digital elevation data (slope, aspect, topographic wetness index, and stream power index), showing significant differences between MRB and PRB, are useful in soil conservation plans. The study highlighted the variation in morphometric parameters with respect to the dissimilarities in topography and climate.