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The use of plants as green manure may be an alternative to improve soil fertility in the region, but the release of nutrients to the soil will depend on the concentrations of lignin, polyphenols (PP), and nitrogen of the green manures used. These variables were analyzed for 24 plant species commonly found in farms of the semi-arid region of NE Brazil, and the relationship between plant biomass quality and N release after incorporation into the soil was evaluated. There was a large variation in the concentration of lignin, PP and N of the green manures tested but these variables presented a low correlation with N mineralization after incorporation to the soil. In order to try to identify patterns among the different manures regarding quality and N release, these were grouped using Principal Component Analysis techniques, but very little meaningful patterns were observed to help predict N release based on the quality of the materials. The lignin content of the materials played an important role to form different groups, but may be the short time of the incubations (28 days) did not allow for the development of the correlation between lignin content and N release. In general, it was observed that all materials that presented a PP/N ratio lower than 0.5 mineralized N, while those that presented values of this ratio above 5 caused N immobilization.