Arid
DOI10.1029/2010JD014788
A comparison of Arctic BrO measurements by chemical ionization mass spectrometry and long path-differential optical absorption spectroscopy
Liao, J.1; Sihler, H.4,6; Huey, L. G.1; Neuman, J. A.5; Tanner, D. J.1; Friess, U.4; Platt, U.4; Flocke, F. M.3; Orlando, J. J.3; Shepson, P. B.7; Beine, H. J.2; Weinheimer, A. J.3; Sjostedt, S. J.8; Nowak, J. B.5; Knapp, D. J.3; Staebler, R. M.9; Zheng, W.3; Sander, R.6; Hall, S. R.3; Ullmann, K.3
通讯作者Liao, J.
来源期刊JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES
ISSN2169-897X
出版年2011
卷号116
英文摘要

A measurement intensive was carried out in Barrow, Alaska, in spring 2009 as part of the Ocean-Atmosphere-Sea-Ice-Snowpack (OASIS) program. The central focus of this campaign was the role of halogen chemistry in the Arctic. A chemical ionization mass spectrometer (CIMS) performed in situ bromine oxide (BrO) measurements. In addition, a long path-differential optical absorption spectrometer (LP-DOAS) measured the average concentration of BrO along light paths of either 7.2 or 2.1 km. A comparison of the 1 min observations from both instruments is presented in this work. The two measurements were highly correlated and agreed within their uncertainties (R-2 = 0.74, slope = 1.10, and intercept = -0.15 pptv). Better correlation was found (R-2 = 0.85, slope = 1.04, and intercept = -0.11 pptv) for BrO observations at moderate wind speeds (>3 m s(-1) and <8 m s(-1)) and low nitric oxide (NO) mixing ratios (<100 pptv). The improved agreement is likely due to the elimination of periods when the spatial distribution of BrO is inhomogeneous. The detection limit obtained for the CIMS was 2.6 pptv (3 sigma) for a 4 s integration period, and the estimated uncertainty was similar to 30%. The detection limits for the LP-DOAS ranged from 0.7 to 5 pptv (3 sigma) depending on the level of ambient light and the chosen light path, and the estimated systematic error was 10%. The agreement between the CIMS and LP-DOAS is excellent and demonstrates the capability of both instruments to selectively and accurately measure BrO with high sensitivity.


类型Article
语种英语
国家USA ; Germany ; Canada
收录类别SCI-E
WOS记录号WOS:000286057400002
WOS关键词IN-SITU MEASUREMENTS ; SURFACE OZONE MEASUREMENTS ; SENSING REFERENCE DATA ; LIGHT-EMITTING-DIODES ; 231-794 NM RANGE ; CROSS-SECTIONS ; TROPOSPHERIC BRO ; ATMOSPHERIC MERCURY ; DEPLETION EVENTS ; GASEOUS MERCURY
WOS类目Meteorology & Atmospheric Sciences
WOS研究方向Meteorology & Atmospheric Sciences
来源机构University of California, Davis
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/169205
作者单位1.Georgia Inst Technol, Sch Earth & Atmospher Sci, Atlanta, GA 30332 USA;
2.Univ Calif Davis, Dept Land Air & Water Resources, Davis, CA 95616 USA;
3.Natl Ctr Atmospher Res, NESL, Div Atmospher Chem, Boulder, CO 80307 USA;
4.Univ Heidelberg, Inst Environm Phys, D-69120 Heidelberg, Germany;
5.Univ Colorado, Cooperat Inst Res Environm Sci, Boulder, CO 80309 USA;
6.Max Planck Inst Chem, D-55020 Mainz, Germany;
7.Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA;
8.Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada;
9.Environm Canada, Sci & Technol Branch, Toronto, ON M3H 5T4, Canada
推荐引用方式
GB/T 7714
Liao, J.,Sihler, H.,Huey, L. G.,et al. A comparison of Arctic BrO measurements by chemical ionization mass spectrometry and long path-differential optical absorption spectroscopy[J]. University of California, Davis,2011,116.
APA Liao, J..,Sihler, H..,Huey, L. G..,Neuman, J. A..,Tanner, D. J..,...&Ullmann, K..(2011).A comparison of Arctic BrO measurements by chemical ionization mass spectrometry and long path-differential optical absorption spectroscopy.JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES,116.
MLA Liao, J.,et al."A comparison of Arctic BrO measurements by chemical ionization mass spectrometry and long path-differential optical absorption spectroscopy".JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES 116(2011).
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