Knowledge Resource Center for Ecological Environment in Arid Area
DOI | 10.1029/2011JD016181 |
Soluble, light-absorbing species in snow at Barrow, Alaska | |
Beine, Harry1; Anastasio, Cort1; Esposito, Giulio2; Patten, Kelley1; Wilkening, Elizabeth3; Domine, Florent4,5,6; Voisin, Didier4,5; Barret, Manuel4,5; Houdier, Stephan4,5; Hall, Sam7 | |
通讯作者 | Beine, Harry |
来源期刊 | JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES
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ISSN | 2169-897X |
EISSN | 2169-8996 |
出版年 | 2011 |
卷号 | 116 |
英文摘要 | As part of the international multidisciplinary Ocean - Atmosphere - Sea Ice - Snowpack (OASIS) program we analyzed more than 500 terrestrial (melted) snow samples near Barrow, AK between February and April 2009 for light absorption, as well as H2O2 and inorganic anion concentrations. For light absorption in the photochemically active region (300-450 nm) of surface snows, H2O2 and NO3- make minor contributions (combined < 9% typically), while HUmic LIke Substances (HULIS) and unknown chromophores each account for approximately half of the total absorption. We have identified four main sources for our residual chromophores (i.e., species other than H-2(2)O or NO3-): (1) vegetation and organic debris impact mostly the lowest 20 cm of the snowpack, (2) marine inputs, which are identified by high Cl- and SO42- contents, (3) deposition of diamond dust to surface snow, and (4) gas-phase exchange between the atmosphere and surface snow layers. The snow surfaces, and accompanying chromophore concentrations, are strongly modulated by winds and snowfall at Barrow. However, even with these physical controls on light absorption, we see an overall decline of light absorption in near-surface snow during the 7 weeks of our campaign, likely due to photo-bleaching of chromophores. While HULIS and unknown chromophores dominate light absorption by soluble species in Barrow snow, we know little about the photochemistry of these species, and thus we as a community are probably overlooking many snowpack photochemical reactions. |
类型 | Article |
语种 | 英语 |
国家 | USA ; Italy ; France ; Canada |
收录类别 | SCI-E |
WOS记录号 | WOS:000295536700003 |
WOS关键词 | UV MOLAR ABSORPTIVITIES ; HYDROGEN-PEROXIDE ; ORGANIC-COMPOUNDS ; HUMIC-LIKE ; SEA-ICE ; PHOTOLYSIS ; TEMPERATURE ; HYDRATION ; NITRITE ; NITRATE |
WOS类目 | Meteorology & Atmospheric Sciences |
WOS研究方向 | Meteorology & Atmospheric Sciences |
来源机构 | University of California, Davis ; E17 |
资源类型 | 期刊论文 |
条目标识符 | http://119.78.100.177/qdio/handle/2XILL650/169182 |
作者单位 | 1.Univ Calif Davis, Dept Land Air & Water Resources, Davis, CA 95616 USA; 2.CNR IIA, I-00015 Rome, Italy; 3.Wilson K8 Sch, Tucson, AZ 85742 USA; 4.CNRS INSU, Lab Glaciol & Geophys Environm, F-38402 St Martin Dheres, France; 5.Univ Grenoble 1, F-38402 St Martin Dheres, France; 6.Univ Laval, CNRS UMI Takuvik 3376, Quebec City, PQ G1V 0A6, Canada; 7.NCAR, Atmosphere & Chem Div, Boulder, CO 80301 USA |
推荐引用方式 GB/T 7714 | Beine, Harry,Anastasio, Cort,Esposito, Giulio,et al. Soluble, light-absorbing species in snow at Barrow, Alaska[J]. University of California, Davis, E17,2011,116. |
APA | Beine, Harry.,Anastasio, Cort.,Esposito, Giulio.,Patten, Kelley.,Wilkening, Elizabeth.,...&Hall, Sam.(2011).Soluble, light-absorbing species in snow at Barrow, Alaska.JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES,116. |
MLA | Beine, Harry,et al."Soluble, light-absorbing species in snow at Barrow, Alaska".JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES 116(2011). |
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Soluble, light-absor(2141KB) | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | 浏览 |
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