Arid
DOI10.1029/2011JD016181
Soluble, light-absorbing species in snow at Barrow, Alaska
Beine, Harry1; Anastasio, Cort1; Esposito, Giulio2; Patten, Kelley1; Wilkening, Elizabeth3; Domine, Florent4,5,6; Voisin, Didier4,5; Barret, Manuel4,5; Houdier, Stephan4,5; Hall, Sam7
通讯作者Beine, Harry
来源期刊JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES
ISSN2169-897X
EISSN2169-8996
出版年2011
卷号116
英文摘要

As part of the international multidisciplinary Ocean - Atmosphere - Sea Ice - Snowpack (OASIS) program we analyzed more than 500 terrestrial (melted) snow samples near Barrow, AK between February and April 2009 for light absorption, as well as H2O2 and inorganic anion concentrations. For light absorption in the photochemically active region (300-450 nm) of surface snows, H2O2 and NO3- make minor contributions (combined < 9% typically), while HUmic LIke Substances (HULIS) and unknown chromophores each account for approximately half of the total absorption. We have identified four main sources for our residual chromophores (i.e., species other than H-2(2)O or NO3-): (1) vegetation and organic debris impact mostly the lowest 20 cm of the snowpack, (2) marine inputs, which are identified by high Cl- and SO42- contents, (3) deposition of diamond dust to surface snow, and (4) gas-phase exchange between the atmosphere and surface snow layers. The snow surfaces, and accompanying chromophore concentrations, are strongly modulated by winds and snowfall at Barrow. However, even with these physical controls on light absorption, we see an overall decline of light absorption in near-surface snow during the 7 weeks of our campaign, likely due to photo-bleaching of chromophores. While HULIS and unknown chromophores dominate light absorption by soluble species in Barrow snow, we know little about the photochemistry of these species, and thus we as a community are probably overlooking many snowpack photochemical reactions.


类型Article
语种英语
国家USA ; Italy ; France ; Canada
收录类别SCI-E
WOS记录号WOS:000295536700003
WOS关键词UV MOLAR ABSORPTIVITIES ; HYDROGEN-PEROXIDE ; ORGANIC-COMPOUNDS ; HUMIC-LIKE ; SEA-ICE ; PHOTOLYSIS ; TEMPERATURE ; HYDRATION ; NITRITE ; NITRATE
WOS类目Meteorology & Atmospheric Sciences
WOS研究方向Meteorology & Atmospheric Sciences
来源机构University of California, Davis ; E17
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/169182
作者单位1.Univ Calif Davis, Dept Land Air & Water Resources, Davis, CA 95616 USA;
2.CNR IIA, I-00015 Rome, Italy;
3.Wilson K8 Sch, Tucson, AZ 85742 USA;
4.CNRS INSU, Lab Glaciol & Geophys Environm, F-38402 St Martin Dheres, France;
5.Univ Grenoble 1, F-38402 St Martin Dheres, France;
6.Univ Laval, CNRS UMI Takuvik 3376, Quebec City, PQ G1V 0A6, Canada;
7.NCAR, Atmosphere & Chem Div, Boulder, CO 80301 USA
推荐引用方式
GB/T 7714
Beine, Harry,Anastasio, Cort,Esposito, Giulio,et al. Soluble, light-absorbing species in snow at Barrow, Alaska[J]. University of California, Davis, E17,2011,116.
APA Beine, Harry.,Anastasio, Cort.,Esposito, Giulio.,Patten, Kelley.,Wilkening, Elizabeth.,...&Hall, Sam.(2011).Soluble, light-absorbing species in snow at Barrow, Alaska.JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES,116.
MLA Beine, Harry,et al."Soluble, light-absorbing species in snow at Barrow, Alaska".JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES 116(2011).
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