Arid
DOI10.1016/j.jcis.2010.07.070
Patterning dewetting in thin polymer films by spatially directed photocrosslinking
Carroll, Gregory T.1; Turro, Nicholas J.1,2; Koberstein, Jeffrey T.2
通讯作者Carroll, Gregory T.
来源期刊JOURNAL OF COLLOID AND INTERFACE SCIENCE
ISSN0021-9797
出版年2010
卷号351期号:2页码:556-560
英文摘要

In this report we examine the dewetting of spin-cast poly (styrene) films in a confined geometry. We designed a platform for laterally confining PS by photo-patterning crosslinks in spin-coated thin films. Heating the patterned film above the glass transition temperature of PS results in localized dewetting patterns in regions that were not crosslinked, while the crosslinked pattern serves as a rigid barrier that confines the retraction of the uncrosslinked polymer in micron-sized domains. The barriers also provide a favorable surface that the liquid PS wets onto, forming a rim at the boundary of crosslinked and uncrosslinked polymer. The resulting patterns are shown to be dependent on the irradiation and annealing time, the dimensions of the uncrosslinked region and the thickness of the film. (C) 2010 Elsevier Inc. All rights reserved.


英文关键词Dewetting Patterning Photocrosslinking Thin films
类型Article
语种英语
国家USA
收录类别SCI-E
WOS记录号WOS:000282706100032
WOS关键词WATER-REPELLENT ; DESERT BEETLE ; SURFACES ; MICROCHANNELS ; MICROWELLS ; MORPHOLOGY ; ROUGHNESS ; ARRAYS
WOS类目Chemistry, Physical
WOS研究方向Chemistry
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/165088
作者单位1.Columbia Univ, Dept Chem, New York, NY 10027 USA;
2.Columbia Univ, Dept Chem Engn, New York, NY 10027 USA
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GB/T 7714
Carroll, Gregory T.,Turro, Nicholas J.,Koberstein, Jeffrey T.. Patterning dewetting in thin polymer films by spatially directed photocrosslinking[J],2010,351(2):556-560.
APA Carroll, Gregory T.,Turro, Nicholas J.,&Koberstein, Jeffrey T..(2010).Patterning dewetting in thin polymer films by spatially directed photocrosslinking.JOURNAL OF COLLOID AND INTERFACE SCIENCE,351(2),556-560.
MLA Carroll, Gregory T.,et al."Patterning dewetting in thin polymer films by spatially directed photocrosslinking".JOURNAL OF COLLOID AND INTERFACE SCIENCE 351.2(2010):556-560.
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