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DOI | 10.1002/hlca.200900136 |
Stereoselective Total Synthesis of (11 beta)-11-Methoxycurvularin | |
Rajesh, Karuturi; Suresh, Vangaru; Selvam, Jondoss Jon Paul; Babu, Dokuburra Chanti; Venkateswarlu, Yenamandra | |
通讯作者 | Venkateswarlu, Yenamandra |
来源期刊 | HELVETICA CHIMICA ACTA
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ISSN | 0018-019X |
EISSN | 1522-2675 |
出版年 | 2010 |
卷号 | 93期号:1页码:147-152 |
英文摘要 | A simple and highly efficient stereoselective total synthesis of (11 beta)-11-methoxycurvularin (5), a polyketide natural product, was achieved. The synthesis commenced with a Cu-mediated regioselective opening of (2S)-2-methyloxirane (6) and comprised a Keck asymmetric allylation and intramolecular Friedel-Crafts acylation as key steps (Scheme 2). |
类型 | Article |
语种 | 英语 |
国家 | India |
收录类别 | SCI-E |
WOS记录号 | WOS:000274284000018 |
WOS关键词 | CATALYTIC ASYMMETRIC ALLYLATION ; CONCISE TOTAL-SYNTHESIS ; SONORAN DESERT ; CURVULARIN ; METABOLITES ; RHIZOSPHERE ; CHEMISTRY |
WOS类目 | Chemistry, Multidisciplinary |
WOS研究方向 | Chemistry |
资源类型 | 期刊论文 |
条目标识符 | http://119.78.100.177/qdio/handle/2XILL650/164432 |
作者单位 | Indian Inst Chem Technol, Nat Prod Lab, Organ Chem Div 1, Hyderabad 500007, Andhra Pradesh, India |
推荐引用方式 GB/T 7714 | Rajesh, Karuturi,Suresh, Vangaru,Selvam, Jondoss Jon Paul,et al. Stereoselective Total Synthesis of (11 beta)-11-Methoxycurvularin[J],2010,93(1):147-152. |
APA | Rajesh, Karuturi,Suresh, Vangaru,Selvam, Jondoss Jon Paul,Babu, Dokuburra Chanti,&Venkateswarlu, Yenamandra.(2010).Stereoselective Total Synthesis of (11 beta)-11-Methoxycurvularin.HELVETICA CHIMICA ACTA,93(1),147-152. |
MLA | Rajesh, Karuturi,et al."Stereoselective Total Synthesis of (11 beta)-11-Methoxycurvularin".HELVETICA CHIMICA ACTA 93.1(2010):147-152. |
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