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The Pan-African Kid-Malhak Dokhan volcanic suite (609 +/- 12 Ma) is exposed in the northernmost part of the Arabian-Nubian Shield. The suite consists of non-metamorphosed varicolored alternating succession of porphyritic lava flows of commonly felsic composition (rhyolite-dacite) interlayered with compositionally equivalent pyroclastic beds (dominantly ignimbrites). These Dokhan volcanics are quite evolved (SiO2 approximate to 65-77 wt.%), with strong high-K calc-alkaline affinity and are characterized by relative enrichment in total alkalis, Ba, Y, Zr and total REEs, depletion in Sr, and a LREE-enriched REE patterns with significant negative Eu anomalies. The Kid-Malhak Dokhan lavas display geochemical characteristics of both orogenic arc-type and anorogenic within-plate environments, suggesting eruption in a transitional "post-collisional tectonic setting. The ages of emplacement of the Dokhan volcanics in Egypt including that of Kid-Malhak region (580-620 Ma) coincide with end of the documented collision between the juvenile Arabian-Nubian crust and Saharan Metacraton and the subsequent extensional collapse event. This post-collision transition from compression to extension is explained by the extensional collapse following continental collision, which was controlled mainly by lithospheric delamination and slab breakoff (passive rifting). Various trace element characteristics discussed herein have indicated that the studied Dokhan magma was highly likely generated from crustal sources and that assimilation-fractional crystallization (AFC) and crustal contamination have played a major role and are most probably superimposed on fractional crystallization during the magmatic evolution of Kid-Malhak Dokhan volcanic suite. The eruption of the high-K calc-alkaline post-collisional Dokhan volcanics in Egypt defines a tectono-magmatic transition between the older calc-alkaline arc-related and the subsequent alkaline magmatism in the northern part of the Arabian-Nubian Shield. (C) 2009 Published by Elsevier B.V. on behalf of International Association for Gondwana Research.