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Calcite and gypsum are salts of major ions characterized by poor solubility compared with other salts that may precipitate in soils. Knowledge of calcite and gypsum solubility products in water-saturated soil samples substantially contributes to a better assessment of processes involved in soil salinity. The new SALSOLCHEMIS code for chemical equilibrium assessment was parameterized with published analytical data for aqueous synthetic calcite and gypsum-saturated solutions. Once parameterized, SALSOLCHEMIS was applied to calculations of the ionic activity products of calcium carbonate and calcium sulphate in 133 water-saturated soil samples from an irrigated salt-affected agricultural area in a semi-arid Mediterranean climate. During parameterization, sufficiently constant values for the ionic activity products of calcium carbonate and calcium sulphate were obtained only when the following were used in SALSOLCHEMIS: (i) the equations of Sposito & Traina for the free ion activity coefficient calculation, (ii) the assumption of the non-existence of the ;Ca(HCO3)(+) and CaCO3o ion pairs and (iii) a paradigm of total ion activity coefficients. The value of 4.62 can be assumed to be a reliable gypsum solubility product (pKs) in simple aqueous and soil solutions, while a value of 8.43 can only be assumed as a reliable calcite solubility product (pKs) in simple aqueous solutions. The saturated pastes and saturation extracts were found to be calcite over-saturated, with the former significantly being less so (pIAP = 8.29) than the latter (pIAP = 8.22). The calcite over-saturation of saturated pastes increased with the soil organic matter content. Nevertheless, the inhibition of calcite precipitation is caused by the soluble organic matter from a dissolved organic carbon threshold value that lies between 7 and 12 mm. The hypothesis of thermodynamic equilibrium is more adequate for the saturated pastes than for the saturation extracts.