Arid
DOI10.1016/j.tetlet.2009.04.120
Stereoselective syntheses of 11-alpha-methoxycurvularin and 11-beta-methoxycurvularin
Reddy, G. Venkateswar; Kumar, R. Sateesh Chandra; Babu, K. Suresh; Rao, J. Madhusudana
通讯作者Rao, J. Madhusudana
来源期刊TETRAHEDRON LETTERS
ISSN0040-4039
出版年2009
卷号50期号:28页码:4117-4120
英文摘要

A stereoselective synthesis of potent cytotoxic macrolides, 11-alpha-methoxycurvularin and 11-beta-methoxycurvularin has been accomplished. The synthesis entailed Maruoka asymmetric allylation to introduce the stereocentres at C-11 and the key fragment was installed by using Grubbs cross-metathesis followed by CBS-reduction. (C) 2009 Published by Elsevier Ltd.


英文关键词Curvularins Macrolides Maruoka asymmetric allylation Grubbs cross-metathesis CBS-reduction
类型Article
语种英语
国家India
收录类别SCI-E
WOS记录号WOS:000267672500030
WOS关键词XESTODECALACTONE-A ; SONORAN DESERT ; CURVULARIN ; STEREOCHEMISTRY ; RHIZOSPHERE ; METABOLITES ; METATHESIS ; INHIBITOR ; ACID
WOS类目Chemistry, Organic
WOS研究方向Chemistry
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/162717
作者单位Indian Inst Chem Technol, Nat Prod Lab, Div Organ Chem 1, Hyderabad 500607, Andhra Pradesh, India
推荐引用方式
GB/T 7714
Reddy, G. Venkateswar,Kumar, R. Sateesh Chandra,Babu, K. Suresh,et al. Stereoselective syntheses of 11-alpha-methoxycurvularin and 11-beta-methoxycurvularin[J],2009,50(28):4117-4120.
APA Reddy, G. Venkateswar,Kumar, R. Sateesh Chandra,Babu, K. Suresh,&Rao, J. Madhusudana.(2009).Stereoselective syntheses of 11-alpha-methoxycurvularin and 11-beta-methoxycurvularin.TETRAHEDRON LETTERS,50(28),4117-4120.
MLA Reddy, G. Venkateswar,et al."Stereoselective syntheses of 11-alpha-methoxycurvularin and 11-beta-methoxycurvularin".TETRAHEDRON LETTERS 50.28(2009):4117-4120.
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