Arid
DOI10.1039/b901585j
Water uptake of clay and desert dust aerosol particles at sub- and supersaturated water vapor conditions
Herich, Hanna1; Tritscher, Torsten2; Wiacek, Aldona1; Gysel, Martin2; Weingartner, Ernest2; Lohmann, Ulrike1; Baltensperger, Urs2; Cziczo, Daniel J.1
通讯作者Cziczo, Daniel J.
来源期刊PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN1463-9076
EISSN1463-9084
出版年2009
卷号11期号:36页码:7804-7809
英文摘要

Airborne mineral dust particles serve as cloud condensation nuclei (CCN), thereby influencing the formation and properties of warm clouds. It is therefore of atmospheric interest how dust aerosols with different mineralogy behave when exposed to high relative humidity (RH) or supersaturation (SS) with respect to liquid water. In this study the subsaturated hygroscopic growth and the supersaturated cloud condensation nucleus activity of pure clays and real desert dust aerosols were determined using a hygroscopicity tandem differential mobility analyzer (HTDMA) and a cloud condensation nuclei counter (CCNC), respectively. Five different illite, montmorillonite and kaolinite clay samples as well as three desert dust samples (Saharan dust (SD), Chinese dust (CD) and Arizona test dust (ATD)) were investigated. Aerosols were generated both with a wet and a dry disperser. The water uptake was parameterized via the hygroscopicity parameter kappa. The hygroscopicity of dry generated dust aerosols was found to be negligible when compared to processed atmospheric aerosols, with CCNC derived kappa values between 0.00 and 0.02 (the latter corresponds to a particle consisting of 96.7% by volume insoluble material and similar to 3.3% ammonium sulfate). Pure clay aerosols were generally found to be less hygroscopic than natural desert dust particles. The illite and montmorillonite samples had kappa similar to 0.003. The kaolinite samples were less hygroscopic and had kappa = 0.001. SD (kappa = 0.023) was found to be the most hygroscopic dry-generated desert dust followed by CD (kappa = 0.007) and ATD (kappa = 0.003). Wet-generated dust showed an increased water uptake when compared to dry-generated samples. This is considered to be an artifact introduced by redistribution of soluble material between the particles. Thus, the generation method is critically important when presenting such data. These results indicate any atmospheric processing of a fresh mineral dust particle which leads to the addition of more than similar to 3% soluble material will significantly enhance its hygroscopicity and CCN activity.


类型Article
语种英语
国家Switzerland
收录类别SCI-E
WOS记录号WOS:000269548300005
WOS关键词MINERAL DUST ; ICE NUCLEATION ; CLOUDS ; CLIMATE ; NUCLEI ; PRECIPITATION ; GROWTH ; DISTRIBUTIONS ; SURFACES ; CHAMBER
WOS类目Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS研究方向Chemistry ; Physics
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/162192
作者单位1.ETH, Inst Atmospher & Climate Sci, CH-8092 Zurich, Switzerland;
2.Paul Scherrer Inst, Lab Atmospher Chem, CH-5232 Villigen, Switzerland
推荐引用方式
GB/T 7714
Herich, Hanna,Tritscher, Torsten,Wiacek, Aldona,et al. Water uptake of clay and desert dust aerosol particles at sub- and supersaturated water vapor conditions[J],2009,11(36):7804-7809.
APA Herich, Hanna.,Tritscher, Torsten.,Wiacek, Aldona.,Gysel, Martin.,Weingartner, Ernest.,...&Cziczo, Daniel J..(2009).Water uptake of clay and desert dust aerosol particles at sub- and supersaturated water vapor conditions.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,11(36),7804-7809.
MLA Herich, Hanna,et al."Water uptake of clay and desert dust aerosol particles at sub- and supersaturated water vapor conditions".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 11.36(2009):7804-7809.
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