Arid
DOI10.1016/j.fuproc.2007.11.022
Transformer oils prepared from the vacuum distillates of Egyptian crude paraffinic petroleum
El-Gayar, M. Sh.; Gohar, G. A.; Ibrahim, A. M.; Ibrahim, H. M.; Aly, A. M.
通讯作者El-Gayar, M. Sh.
来源期刊FUEL PROCESSING TECHNOLOGY
ISSN0378-3820
EISSN1873-7188
出版年2008
卷号89期号:3页码:254-261
英文摘要

Vacuum gas oil and spindle oil obtained from the vacuum distillation of paraffinic crude oil from the Western Desert region of Egypt were utilized for transformer oils production. The vacuum gas oil, spindle oil and blends therefrom containing different percentages of these oils and were subjected to aromatic extraction, dewaxing catalytic hydrogenation processes. The aromatic extraction process used N-methyl-2-pyrrolidone as solvent, for a feed ratio of 0.7:1 (wt/wt) at an extraction temperature of 55 degrees C, while in the dewaxing process the wax is removed by chilling the raffinate at -42 degrees C using MEK-toluene (60:40,vol/vol). The hydrofinishing process was achieved in a pilot plant using NiO-MoO3/Al2O3 catalyst. These refining processes improved the viscosity indices and the pour points of the resulting oils and removed most of the polar impurities. It was found that, the transformer oil formulated from 7:3 b.w. vacuum gas oil:spindle oil respectively meets the IEC 60296-2003 standard specifications requirements. Its sulfur content is very low and non-corrosive. The gassing tendency is also low due to its low aromatic content. Further, the electrical properties which are significant for transformer oils fulfill the standard specifications as a result of the low water content and polar contaminants. Moreover, addition of 2,4-dimethyl-6-tertiary butyl phenol increases the oxidation stability of the produced oil, by acting as a free radical inhibitor. (c) 2007 Elsevier B.V. All rights reserved.


英文关键词transformer oils vacuum gas oil spindle oil petroleum refining anti-oxidants specifications of transformer oils
类型Article
语种英语
国家Egypt
收录类别SCI-E
WOS记录号WOS:000254374900005
WOS类目Chemistry, Applied ; Energy & Fuels ; Engineering, Chemical
WOS研究方向Chemistry ; Energy & Fuels ; Engineering
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/157342
作者单位Univ Alexandria, Fac Sci, Dept Chem, Alexandria, Egypt
推荐引用方式
GB/T 7714
El-Gayar, M. Sh.,Gohar, G. A.,Ibrahim, A. M.,et al. Transformer oils prepared from the vacuum distillates of Egyptian crude paraffinic petroleum[J],2008,89(3):254-261.
APA El-Gayar, M. Sh.,Gohar, G. A.,Ibrahim, A. M.,Ibrahim, H. M.,&Aly, A. M..(2008).Transformer oils prepared from the vacuum distillates of Egyptian crude paraffinic petroleum.FUEL PROCESSING TECHNOLOGY,89(3),254-261.
MLA El-Gayar, M. Sh.,et al."Transformer oils prepared from the vacuum distillates of Egyptian crude paraffinic petroleum".FUEL PROCESSING TECHNOLOGY 89.3(2008):254-261.
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