Arid
DOI10.1029/2006JG000329
Organic amine biomarker detection in the Yungay region of the Atacama Desert with the Urey instrument
Skelley, Alison M.; Aubrey, Andrew D.; Willis, Peter A.; Amashukeli, Xenia; Ehrenfreund, Pascale; Bada, Jeffrey L.; Grunthaner, Frank J.; Mathies, Richard A.
通讯作者Skelley, Alison M.
来源期刊JOURNAL OF GEOPHYSICAL RESEARCH-BIOGEOSCIENCES
ISSN2169-8953
EISSN2169-8961
出版年2007
卷号112期号:G4
英文摘要

The Urey in situ organic compound analysis instrument, consisting of a subcritical water extractor ( SCWE) and a portable microchip capillary electrophoresis instrument called the Mars Organic Analyzer ( MOA), was field tested in the Atacama Desert, Chile, in June 2005. Soil samples from the most arid Yungay region were collected, biomarkers were extracted by the SCWE, and organic amine composition and amino acid chirality analysis was performed by the MOA. Samples collected from the top 1 cm of duracrust soil but shielded from the ambient environment by rocks were compared to the exposed duracrust. The shielded duracrust yielded amines and amino acids ranging from 50 to 100 ppb, while amino acid signals from the exposed duracrust were below blank levels. Samples from buried gypsum deposits located directly above a water flow channel contained amino acids ranging from 13 to 90 ppb. Chiral analysis revealed D/L ratios of 0.39 +/- 0.08 and 0.34 +/- 0.07 for alanine/serine and 0.78 +/- 0.06 for aspartic acid, indicating significant racemization of biologically produced amino acids. On the basis of the D/L ratios, we estimate sample ages ranging from 10(3) to 10(5) years. These results demonstrate the successful field testing of the Urey instrument, as well as the detection of biomarkers from past terrestrial life in one of the most arid and Mars-like regions on Earth.


类型Article
语种英语
国家USA ; Netherlands
收录类别SCI-E
WOS记录号WOS:000249030300001
WOS关键词SOIL-WATER BALANCE ; MERIDIANI-PLANUM ; ACID RACEMIZATION ; MARS ; LIFE ; PRESERVATION ; EXPLORATION ; SEARCH ; CHILE ; ROVER
WOS类目Environmental Sciences ; Geosciences, Multidisciplinary
WOS研究方向Environmental Sciences & Ecology ; Geology
来源机构University of California, Berkeley
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/155077
作者单位(1)Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA;(2)Univ Calif San Diego, Scripps Inst Oceanog, La Jolla, CA 92093 USA;(3)CALTECH, Jet Propuls Lab, Pasadena, CA 91109 USA;(4)Leiden Univ, Leiden Inst Chem, Astrobiol Lab, NL-2300 RA Leiden, Netherlands
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GB/T 7714
Skelley, Alison M.,Aubrey, Andrew D.,Willis, Peter A.,et al. Organic amine biomarker detection in the Yungay region of the Atacama Desert with the Urey instrument[J]. University of California, Berkeley,2007,112(G4).
APA Skelley, Alison M..,Aubrey, Andrew D..,Willis, Peter A..,Amashukeli, Xenia.,Ehrenfreund, Pascale.,...&Mathies, Richard A..(2007).Organic amine biomarker detection in the Yungay region of the Atacama Desert with the Urey instrument.JOURNAL OF GEOPHYSICAL RESEARCH-BIOGEOSCIENCES,112(G4).
MLA Skelley, Alison M.,et al."Organic amine biomarker detection in the Yungay region of the Atacama Desert with the Urey instrument".JOURNAL OF GEOPHYSICAL RESEARCH-BIOGEOSCIENCES 112.G4(2007).
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