Knowledge Resource Center for Ecological Environment in Arid Area
DOI | 10.1029/2006JG000329 |
Organic amine biomarker detection in the Yungay region of the Atacama Desert with the Urey instrument | |
Skelley, Alison M.; Aubrey, Andrew D.; Willis, Peter A.; Amashukeli, Xenia; Ehrenfreund, Pascale; Bada, Jeffrey L.; Grunthaner, Frank J.; Mathies, Richard A. | |
通讯作者 | Skelley, Alison M. |
来源期刊 | JOURNAL OF GEOPHYSICAL RESEARCH-BIOGEOSCIENCES
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ISSN | 2169-8953 |
EISSN | 2169-8961 |
出版年 | 2007 |
卷号 | 112期号:G4 |
英文摘要 | The Urey in situ organic compound analysis instrument, consisting of a subcritical water extractor ( SCWE) and a portable microchip capillary electrophoresis instrument called the Mars Organic Analyzer ( MOA), was field tested in the Atacama Desert, Chile, in June 2005. Soil samples from the most arid Yungay region were collected, biomarkers were extracted by the SCWE, and organic amine composition and amino acid chirality analysis was performed by the MOA. Samples collected from the top 1 cm of duracrust soil but shielded from the ambient environment by rocks were compared to the exposed duracrust. The shielded duracrust yielded amines and amino acids ranging from 50 to 100 ppb, while amino acid signals from the exposed duracrust were below blank levels. Samples from buried gypsum deposits located directly above a water flow channel contained amino acids ranging from 13 to 90 ppb. Chiral analysis revealed D/L ratios of 0.39 +/- 0.08 and 0.34 +/- 0.07 for alanine/serine and 0.78 +/- 0.06 for aspartic acid, indicating significant racemization of biologically produced amino acids. On the basis of the D/L ratios, we estimate sample ages ranging from 10(3) to 10(5) years. These results demonstrate the successful field testing of the Urey instrument, as well as the detection of biomarkers from past terrestrial life in one of the most arid and Mars-like regions on Earth. |
类型 | Article |
语种 | 英语 |
国家 | USA ; Netherlands |
收录类别 | SCI-E |
WOS记录号 | WOS:000249030300001 |
WOS关键词 | SOIL-WATER BALANCE ; MERIDIANI-PLANUM ; ACID RACEMIZATION ; MARS ; LIFE ; PRESERVATION ; EXPLORATION ; SEARCH ; CHILE ; ROVER |
WOS类目 | Environmental Sciences ; Geosciences, Multidisciplinary |
WOS研究方向 | Environmental Sciences & Ecology ; Geology |
来源机构 | University of California, Berkeley |
资源类型 | 期刊论文 |
条目标识符 | http://119.78.100.177/qdio/handle/2XILL650/155077 |
作者单位 | (1)Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA;(2)Univ Calif San Diego, Scripps Inst Oceanog, La Jolla, CA 92093 USA;(3)CALTECH, Jet Propuls Lab, Pasadena, CA 91109 USA;(4)Leiden Univ, Leiden Inst Chem, Astrobiol Lab, NL-2300 RA Leiden, Netherlands |
推荐引用方式 GB/T 7714 | Skelley, Alison M.,Aubrey, Andrew D.,Willis, Peter A.,et al. Organic amine biomarker detection in the Yungay region of the Atacama Desert with the Urey instrument[J]. University of California, Berkeley,2007,112(G4). |
APA | Skelley, Alison M..,Aubrey, Andrew D..,Willis, Peter A..,Amashukeli, Xenia.,Ehrenfreund, Pascale.,...&Mathies, Richard A..(2007).Organic amine biomarker detection in the Yungay region of the Atacama Desert with the Urey instrument.JOURNAL OF GEOPHYSICAL RESEARCH-BIOGEOSCIENCES,112(G4). |
MLA | Skelley, Alison M.,et al."Organic amine biomarker detection in the Yungay region of the Atacama Desert with the Urey instrument".JOURNAL OF GEOPHYSICAL RESEARCH-BIOGEOSCIENCES 112.G4(2007). |
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