Arid
DOI10.1016/j.jconhyd.2005.07.005
Modelling field-scale cadmium transport below the root zone of a sewage sludge amended soil in an arid region in Central Iran
Moradi, AB; Abbaspour, KC; Afyuni, M
通讯作者Moradi, AB
来源期刊JOURNAL OF CONTAMINANT HYDROLOGY
ISSN0169-7722
出版年2005
卷号79期号:3-4页码:187-206
英文摘要

Addition of trace metals such as cadmium to soils in metal-rich sewage Sludge may result in contamination of soil and groundwater. This study addresses the plot-scale transport of Cd derived from sewage Sludge in a layered clay soil in all arid region of central Iran. Sewage Sludge was enriched by Cd at rates of 38 and 80 mg kg(-1) and applied to experimental soil plots using a complete random block design with three replicates. Cadmium concentration was measured as a function of depth after 185 and 617 days. HYDRUS-1D and MACRO codes were calibrated for Cd transport in the site treated with 80 mg kg(-1) sewage Sludge. Model parameters were estimated by inverse modelling Using the SUFI-2 procedure. The site treated with 38 mg kg(-1) cadmium was used to test the calibrated models. Both convection-dispersion equation (CDE) and non-equilibrium CDE in HYDRUS-1D produced reasonable calibration results. However, the estimated Freundlich sorption constants were significantly smaller than those measured in a batch study. A site tracer experiment revealed the existence Of Substantial macropore flow. For this reason we applied MACRO to account for this process. The calibration and test results with MACRO were as good as those obtained by HYDRUS-1D) with the difference that adsorption constants were much closer to the measured ones. This indicates that in HYDRUS-1D, the adsorption parameters were underestimated in order to allow a deeper transport of Cd which had actually occurred due to macropore flow. A 20-year simulation scenario depicting the long-term effect of sludge application indicated small risk of groundwater contamination. However, high concentration of Cd near the soil surface raises a concern about the crop Cd uptake which should be further investigated. (c) 2005 Elsevier B.V. All rights reserved.


英文关键词cadmium sewage sludge inverse modelling parameter optimization macropore flow
类型Article
语种英语
国家Switzerland ; Iran
收录类别SCI-E
WOS记录号WOS:000232844600005
WOS关键词HEAVY-METAL DISPLACEMENT ; DUAL-POROSITY MODEL ; POROUS-MEDIA ; SANDY SOIL ; HYDRAULIC CONDUCTIVITY ; AGRICULTURAL USE ; SORPTION ; NONEQUILIBRIUM ; MOVEMENT ; EXTRACTABILITY
WOS类目Environmental Sciences ; Geosciences, Multidisciplinary ; Water Resources
WOS研究方向Environmental Sciences & Ecology ; Geology ; Water Resources
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/149578
作者单位(1)Swiss Fed Inst Technol, Inst Terr Ecol, CH-8952 Schlieren, Switzerland;(2)Swiss Fed Inst Environm Sci & Technol, CH-8600 Dubendorf, Switzerland;(3)Isfahan Univ Technol, Coll Agr, Dept Soil Sci, Esfahan 84155, Iran
推荐引用方式
GB/T 7714
Moradi, AB,Abbaspour, KC,Afyuni, M. Modelling field-scale cadmium transport below the root zone of a sewage sludge amended soil in an arid region in Central Iran[J],2005,79(3-4):187-206.
APA Moradi, AB,Abbaspour, KC,&Afyuni, M.(2005).Modelling field-scale cadmium transport below the root zone of a sewage sludge amended soil in an arid region in Central Iran.JOURNAL OF CONTAMINANT HYDROLOGY,79(3-4),187-206.
MLA Moradi, AB,et al."Modelling field-scale cadmium transport below the root zone of a sewage sludge amended soil in an arid region in Central Iran".JOURNAL OF CONTAMINANT HYDROLOGY 79.3-4(2005):187-206.
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