Arid
DOI10.1524/ract.92.9.719.55000
Formation of hydroxyapatite in soils using calcium citrate and sodium phosphate for control of strontium migration
Moore, RC; Sanchez, C; Holt, K; Zhang, PC; Xu, HF; Choppin, GR
通讯作者Moore, RC
来源期刊RADIOCHIMICA ACTA
ISSN0033-8230
出版年2004
卷号92期号:9-11页码:719-723
英文摘要

Sr-90 contamination is a major problem at several U.S. sites. At some sites, Sr-90 has migrated deep underground making site remediation difficult. In this paper, we describe a novel method for precipitation of hydroxyapatite, a strong sorbent for Sr-90, in soil. The method is based on mixing a solution of calcium citrate and sodium phosphate in soil. As the indigenous soil microorganisms mineralize the citrate, the calcium is released and forms hydroxyapatite. Soil, taken from the Albuquerque desert, was treated with a sodium phosphate Solution or a sodium phosphate/calcium citrate solution. TEM and EDS were used to identify hydroxyapatite with CO32- substitutions, with a formula of (Ca4.8Na0.2)[(PO4)(2.8)(CO3)(0.2)](OH), in the soil treated with the sodium phosphate/calcium citrate solution. Untreated and treated soils were used in batch sorption experiments for Sr uptake. Average Sr uptake was 19.5, 77.0 and 94.7% for the untreated soil, soil treated with sodium phosphate, and soil with apatite, respectively. In desorption experiments, the untreated soil, phosphate treated soil and apatite treated soil released an average of 34.2, 28.8 and 4.8% respectively. The results indicate the potential of forming apatite in Soil using soluble reagents for retardation of radionuclide migration.


英文关键词hydroxyapatite apatite soils radionuclide barrier strontium immobilization sorption
类型Article ; Proceedings Paper
语种英语
国家USA
收录类别CPCI-S ; SCI-E
WOS记录号WOS:000225831400029
WOS关键词CONTAMINATED SEDIMENTS ; SYNTHETIC HYDROXYAPATITE ; SORPTION ; URANIUM ; IMMOBILIZATION ; REMEDIATION ; APATITE ; METALS ; PH
WOS类目Chemistry, Inorganic & Nuclear ; Nuclear Science & Technology
WOS研究方向Chemistry ; Nuclear Science & Technology
来源机构University of Arizona
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/147953
作者单位(1)Sandia Natl Labs, Albuquerque, NM 87185 USA;(2)Univ Arizona, Dept Soil Water & Environm Sci, Yuma, AZ 85364 USA;(3)Univ New Mexico, Dept Earth & Planetary Sci, Albuquerque, NM 87131 USA;(4)Florida State Univ, Dept Chem, Gainesville, FL 32606 USA
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Moore, RC,Sanchez, C,Holt, K,et al. Formation of hydroxyapatite in soils using calcium citrate and sodium phosphate for control of strontium migration[J]. University of Arizona,2004,92(9-11):719-723.
APA Moore, RC,Sanchez, C,Holt, K,Zhang, PC,Xu, HF,&Choppin, GR.(2004).Formation of hydroxyapatite in soils using calcium citrate and sodium phosphate for control of strontium migration.RADIOCHIMICA ACTA,92(9-11),719-723.
MLA Moore, RC,et al."Formation of hydroxyapatite in soils using calcium citrate and sodium phosphate for control of strontium migration".RADIOCHIMICA ACTA 92.9-11(2004):719-723.
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