Knowledge Resource Center for Ecological Environment in Arid Area
DOI | 10.1524/ract.92.9.719.55000 |
Formation of hydroxyapatite in soils using calcium citrate and sodium phosphate for control of strontium migration | |
Moore, RC; Sanchez, C; Holt, K; Zhang, PC; Xu, HF; Choppin, GR | |
通讯作者 | Moore, RC |
来源期刊 | RADIOCHIMICA ACTA
![]() |
ISSN | 0033-8230 |
出版年 | 2004 |
卷号 | 92期号:9-11页码:719-723 |
英文摘要 | Sr-90 contamination is a major problem at several U.S. sites. At some sites, Sr-90 has migrated deep underground making site remediation difficult. In this paper, we describe a novel method for precipitation of hydroxyapatite, a strong sorbent for Sr-90, in soil. The method is based on mixing a solution of calcium citrate and sodium phosphate in soil. As the indigenous soil microorganisms mineralize the citrate, the calcium is released and forms hydroxyapatite. Soil, taken from the Albuquerque desert, was treated with a sodium phosphate Solution or a sodium phosphate/calcium citrate solution. TEM and EDS were used to identify hydroxyapatite with CO32- substitutions, with a formula of (Ca4.8Na0.2)[(PO4)(2.8)(CO3)(0.2)](OH), in the soil treated with the sodium phosphate/calcium citrate solution. Untreated and treated soils were used in batch sorption experiments for Sr uptake. Average Sr uptake was 19.5, 77.0 and 94.7% for the untreated soil, soil treated with sodium phosphate, and soil with apatite, respectively. In desorption experiments, the untreated soil, phosphate treated soil and apatite treated soil released an average of 34.2, 28.8 and 4.8% respectively. The results indicate the potential of forming apatite in Soil using soluble reagents for retardation of radionuclide migration. |
英文关键词 | hydroxyapatite apatite soils radionuclide barrier strontium immobilization sorption |
类型 | Article ; Proceedings Paper |
语种 | 英语 |
国家 | USA |
收录类别 | CPCI-S ; SCI-E |
WOS记录号 | WOS:000225831400029 |
WOS关键词 | CONTAMINATED SEDIMENTS ; SYNTHETIC HYDROXYAPATITE ; SORPTION ; URANIUM ; IMMOBILIZATION ; REMEDIATION ; APATITE ; METALS ; PH |
WOS类目 | Chemistry, Inorganic & Nuclear ; Nuclear Science & Technology |
WOS研究方向 | Chemistry ; Nuclear Science & Technology |
来源机构 | University of Arizona |
资源类型 | 期刊论文 |
条目标识符 | http://119.78.100.177/qdio/handle/2XILL650/147953 |
作者单位 | (1)Sandia Natl Labs, Albuquerque, NM 87185 USA;(2)Univ Arizona, Dept Soil Water & Environm Sci, Yuma, AZ 85364 USA;(3)Univ New Mexico, Dept Earth & Planetary Sci, Albuquerque, NM 87131 USA;(4)Florida State Univ, Dept Chem, Gainesville, FL 32606 USA |
推荐引用方式 GB/T 7714 | Moore, RC,Sanchez, C,Holt, K,et al. Formation of hydroxyapatite in soils using calcium citrate and sodium phosphate for control of strontium migration[J]. University of Arizona,2004,92(9-11):719-723. |
APA | Moore, RC,Sanchez, C,Holt, K,Zhang, PC,Xu, HF,&Choppin, GR.(2004).Formation of hydroxyapatite in soils using calcium citrate and sodium phosphate for control of strontium migration.RADIOCHIMICA ACTA,92(9-11),719-723. |
MLA | Moore, RC,et al."Formation of hydroxyapatite in soils using calcium citrate and sodium phosphate for control of strontium migration".RADIOCHIMICA ACTA 92.9-11(2004):719-723. |
条目包含的文件 | 条目无相关文件。 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。