Arid
DOI10.4319/lo.2004.49.3.0756
Variations in the mass-specific absorption coefficient of mineral particles suspended in water
Babin, M; Stramski, D
通讯作者Babin, M
来源期刊LIMNOLOGY AND OCEANOGRAPHY
ISSN0024-3590
出版年2004
卷号49期号:3页码:756-767
英文摘要

We examined the light-absorption properties of various samples of mineral particles suspended in water, which included pure mineral species (quartz, calcite, illite, kaolinite, and montmorillonite) and natural particulate assemblages such as desert dust originating from different locations in the Sahara. The absorption coefficient was measured in the spectral region from ultraviolet (UV) to near-infrared on particle suspensions, using a special measurement geometry that reduced the scattering error to a very small level. The concentrations of the total mass of particles in suspension, as well as the mineralogical and elemental composition of particulate samples, were also determined. For the samples of pure mineral species with negligible contamination with iron, absorption was undetectable in the visible spectral region. All of the examined natural assemblages of mixed mineral species showed a significant content of iron (5-29% by weight), and all these samples exhibited significant absorption in the UV and blue-green (400-550 nm) spectral regions. The spectral shape of absorption was similar to that determined on pure iron hydroxide suspension, with some spectral features (shoulders and changes in slope) superposed onto a general increase of absorption toward short wavelengths in the UV. The mass-specific absorption coefficient of the mineral samples, a(m)*(lambda), obtained by normalization of the absorption coefficient to the dry-mass concentration of particles, showed a significant positive correlation with Fe content. No such relationship was found for other elements present in particles. The range of a*(m)(lambda) values covered more than an order of magnitude (from <0.1 to similar to1 m(2) g(-1) near 400 nm), but the normalization of absorption coefficient to iron concentration led to a considerable reduction in variability among the samples. The iron-specific absorption coefficient, a(Fe)*(lambda),varied from similar to1 to 4 m(2) (g Fe)(-1) near 400 nm for the natural mixtures of mineral species. Although iron was a major pigmenting agent, its concentration could explain only part of variability observed in the absorption properties of mineral particles.


类型Article
语种英语
国家USA
收录类别SCI-E
WOS记录号WOS:000224979600015
WOS关键词INFRARED SPECTRAL REGION ; AQUATIC PARTICLES ; VISIBLE SPECTROSCOPY ; OPTICAL-PROPERTIES ; LIGHT-ABSORPTION ; OXIDE MINERALS ; NORTH-ATLANTIC ; SEA ; PHYTOPLANKTON ; IRON
WOS类目Limnology ; Oceanography
WOS研究方向Marine & Freshwater Biology ; Oceanography
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/147631
作者单位(1)Univ Calif San Diego, Scripps Inst Oceanog, Marine Phys Lab, La Jolla, CA 92093 USA
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Babin, M,Stramski, D. Variations in the mass-specific absorption coefficient of mineral particles suspended in water[J],2004,49(3):756-767.
APA Babin, M,&Stramski, D.(2004).Variations in the mass-specific absorption coefficient of mineral particles suspended in water.LIMNOLOGY AND OCEANOGRAPHY,49(3),756-767.
MLA Babin, M,et al."Variations in the mass-specific absorption coefficient of mineral particles suspended in water".LIMNOLOGY AND OCEANOGRAPHY 49.3(2004):756-767.
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