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About 200 samples from selected public supply, domestic, and observation wells completed in alluvial aquifers underlying the western Mojave Desert were analyzed for total dissolved Cr and Cr(VI). Because Cr(VI) is difficult to preserve, samples were analyzed by 3 methods. Chromium(VI) was determined in the field using both a direct colorimetric method and EPA method 218.6, and samples were speciated in the field for later analysis in the laboratory using a cation-exchange method developed for the study described in this paper. Comparison of the direct colorimetric method and EPA method 218.6 with the new cation-exchange method yielded 12 values of 0.9991 and 0.9992, respectively. Total dissolved Cr concentrations ranged from less than the 0.1 mug/l detection limit to 60 mug/l, and almost all the Cr present was Cr(VI). Near recharge areas along the mountain front pH values were near neutral, dissolved O-2 concentrations were near saturation, and Cr(VI) concentrations were less than the 0.1 mug/l detection limit. Chromium(VI) concentrations and pH values increased downgradient as long as dissolved O-2 was present. However, low Cr(VI) concentrations were associated with low dissolved O-2 concentrations near ground-water discharge areas along dry lakes. Chromium(VI) concentrations as high as 60 mug/l occurred in ground water from the Sheep Creek fan alluvial deposits weathered from mafic rock derived from the San Gabriel Mountains, and Cr(VI) concentrations as high as about 36 mug/l were present in ground water from alluvial deposits weathered from less mafic granitic, metamorphic, and volcanic rocks. Chromium(III) was the predominant form of Cr only in areas where dissolved O-2 concentrations were less than 1 mg/l and was detected at a median concentration of 0.1 mug/l, owing to its low solubility in water of near-neutral pH. Depending on local hydrogeologic conditions and the distribution of dissolved O-2 Cr(VI) concentrations may vary considerably with depth. Samples collected under pumping conditions from different depths within wells show that Cr(VI) concentrations can range from less than the 0.1 mug/l detection limit to 36 mug/l in a single well and that dissolved O-2 concentrations likely control the concentration and redox speciation of Cr in ground water. Published by Elsevier Ltd.