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We discuss properties of the atmospheric water vapor above the high Andean plateau region known as the Llano de Chajnantor, in the Atacama Desert of northern Chile. A combination of radiometric and radiosonde measurements indicates that the median column of precipitable water vapor (PWV) above the plateau at an elevation of 5000 m is approximately 1.2 mm. The exponential scale height of the water vapor density in the median Chajnantor atmosphere is 1.13 km; the median PWV is 0.5 mm above an elevation of 5750 m. Both of these values appear to be lower at night. Annual, diurnal, and other dependences of PWV and its scale height are discussed, as well as the occurrence of temperature inversion layers below the elevation of peaks surrounding the plateau. We estimate the background for infrared observations and sensitivities for broadband and high-resolution spectroscopy. The results suggest that exceptional atmospheric conditions are present in the region, yielding high infrared transparency and high sensitivity for future ground-based infrared telescopes.