Arid
DOI10.1021/es9605533
Sulfate sampling artifact from SO2 and alkaline soil
Eldred, RA; Cahill, TA
通讯作者Eldred, RA
来源期刊ENVIRONMENTAL SCIENCE & TECHNOLOGY
ISSN0013-936X
出版年1997
卷号31期号:5页码:1320-1324
英文摘要

A significant sulfate artifact may be produced by the interaction of SO2(g) with basic particles on filters when the SO2 is not first removed by a denuder. Such an artifact could invalidate most historical sulfate measurements in regions with alkaline soil. To test this hypothesis, we compare measurements from Teflon filters without a denuder to measurements from nylon filters following a carbonate denuder from the Interagency Monitoring of Protected Visual Environments (IMPROVE) network. The data at 11 remote sites in the Desert Southwest show no evidence of a sulfate artifact. Using a normal error distribution, we show that any artifact is much less than 20 ng/m(3). In addition, data from 16 collocated samplers at Meadview, AZ, show that removing the SO2 by denuders does not change the measured sulfate. The mean difference between no-denuder and denuder is -4 +/- 10 ng/m(3) for Teflon filters and 3 +/- 17 ng/m(3) for nylon filters. Brigham Young University obtained large differences between their denuder and filter pack samplers at Meadview. Our analysis shows that these differences are explained better by a bias in their denuder sampler than by an SO2 artifact. Our analysis also shows that their measurements are too imprecise to determine an artifact less than about 500 ng/m(3).


类型Article
语种英语
收录类别SCI-E
WOS记录号WOS:A1997WW94800027
WOS类目Engineering, Environmental ; Environmental Sciences
WOS研究方向Engineering ; Environmental Sciences & Ecology
来源机构University of California, Davis
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/134125
推荐引用方式
GB/T 7714
Eldred, RA,Cahill, TA. Sulfate sampling artifact from SO2 and alkaline soil[J]. University of California, Davis,1997,31(5):1320-1324.
APA Eldred, RA,&Cahill, TA.(1997).Sulfate sampling artifact from SO2 and alkaline soil.ENVIRONMENTAL SCIENCE & TECHNOLOGY,31(5),1320-1324.
MLA Eldred, RA,et al."Sulfate sampling artifact from SO2 and alkaline soil".ENVIRONMENTAL SCIENCE & TECHNOLOGY 31.5(1997):1320-1324.
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