Arid
DOI10.1016/S0009-2541(96)00129-5
Elevated and variable values of C-13 in speleothems in a British cave system
Baker, A; Ito, E; Smart, PL; McEwan, RF
通讯作者Baker, A
来源期刊CHEMICAL GEOLOGY
ISSN0009-2541
出版年1997
卷号136期号:3-4页码:263-270
英文摘要

delta(13)C isotope variations in speleothems have been investigated for samples from the British Isles, where plants which use the Hatch-Slack or C-4 photosynthetic pathway are not present. The range of delta(13)C expected in speleothem carbonate formed in isotopic equilibrium with soil CO2 derived from the overlying C-3 vegetation should thus fall in the range -12 to -6 parts per thousand. Forty-one actively growing speleothem samples from low-discharge sites were analysed from Stump Cross Caverns, Yorkshire, England. Ten percent have delta(13)C greater than -6 parts per thousand. In addition, a large range of delta(13)C was observed (-8.06 +/- 1.38 parts per thousand, a 1 sigma variability of 17%) with adjacent samples having delta(13)C differing by a maximum of 4.74 parts per thousand. Similar findings were obtained from a review of analyses of late Quaternary speleothem samples from the British Isles, with 75% of flowstone samples and 57% of high-flow stalagmite samples exhibiting elevated delta(13)C. Three possible processes are proposed as possible causes of elevated delta(13)C in speleothems. Firstly, fractionation may occur between the stalactite and stalagmite due to evaporation or degassing. Secondly, degassing of the groundwaters may have occurred within the aquifer before reaching the cave void, allowing release of some CO2 from the water whilst remaining saturated in calcium. Finally, the elevated delta(13)C may be due to short water residence times in the soil, such that equilibrium between soil water and soil CO2 is not reached, Evidence presented here demonstrates that any one of these mechanisms may be important in the karst areas of the British Isles. Caution is needed before interpreting the delta(13)C Signal within speleothems in terms of palaeovegetation.


英文关键词C-13 speleothems palaeovegetation isotopes quaternary
类型Article
语种英语
国家USA ; ENGLAND
收录类别SCI-E
WOS记录号WOS:A1997WQ22100006
WOS关键词CARBON-ISOTOPE COMPOSITION ; SOIL CO2 ; CLIMATE ; CALCITE ; FLOW ; PREDICTIONS ; DESERT
WOS类目Geochemistry & Geophysics
WOS研究方向Geochemistry & Geophysics
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/133969
作者单位(1)UNIV MINNESOTA,DEPT GEOL & GEOPHYS,MINNEAPOLIS,MN 55455;(2)UNIV MINNESOTA,LIMNOL RES CTR,MINNEAPOLIS,MN 55455;(3)UNIV BRISTOL,DEPT GEOG,BRISTOL BS8 1SS,AVON,ENGLAND
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Baker, A,Ito, E,Smart, PL,et al. Elevated and variable values of C-13 in speleothems in a British cave system[J],1997,136(3-4):263-270.
APA Baker, A,Ito, E,Smart, PL,&McEwan, RF.(1997).Elevated and variable values of C-13 in speleothems in a British cave system.CHEMICAL GEOLOGY,136(3-4),263-270.
MLA Baker, A,et al."Elevated and variable values of C-13 in speleothems in a British cave system".CHEMICAL GEOLOGY 136.3-4(1997):263-270.
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