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Artificial weathering of the ordinary chondrite Allegan: Implications for the presence of Cl- as a structural component in akaganeite
Bland, PA; Kelley, SP; Berry, FJ; Cadogan, JM; Pillinger, CT
来源期刊AMERICAN MINERALOGIST
ISSN0003-004X
EISSN1945-3027
出版年1997
卷号82期号:11-12页码:1187-1197
英文摘要

A sample of an ordinary chondrite fall, Allegan, was shown by Fe-57 Mossbauer spectroscopy to be unweathered. Using aerated deionized water at 25 degrees and 0 degrees C, and in one case with dissolved salts added, an attempt was made to simulate meteorite weathering processes in the hot and cold desert environments where these samples accumulate. The progress of artificial oxidation was monitored by Fe-57 Mossbauer spectroscopy, and the final products were analyzed by neutron activation. The results confirm weathering mechanisms proposed for naturally weathered meteorites and suggest that temperature is the major factor controlling the stability of the observed oxide mineral assemblage. Akaganeite was observed as a major oxidation product in the experimentally weathered sample. This finding is interesting because it is widely accepted that beta-FeOOH requires Cl- for stability: The sample weathered in deionized water showed only trace amounts of Cl- in both the fresh and weathered meteorite. We suggest that both Cl- and OH- may be effective in filling tunnel sites and that a complete solid solution is possible between these end-members. In addition, a calculated formation age of 4.59 +/- 0.05 Ga and a cosmic-ray exposure age of 5.7-6.2 Ma, was derived from neutron activation analyses of the weathered sample. These ages are consistent with independent measurements made on samples of fresh Allegan, although small sample weights mean that the results should be treated with caution. However, the similar ages obtained in the weathered sample indicates that a wider spectrum of cosmochemical analyses is possible with weathered meteorites than previously thought and that congruent dissolution occurs during meteorite weathering.


类型Article
语种英语
国家ENGLAND ; AUSTRALIA
收录类别SCI-E
WOS记录号WOS:A1997YG09400015
WOS关键词RAY PRODUCTION-RATES ; MOSSBAUER-SPECTROSCOPY ; DISSOLUTION KINETICS ; BETA-FEOOH ; METEORITES ; SILICATES ; MECHANISM ; MINERALS ; CHLORIDE ; OLIVINE
WOS类目Geochemistry & Geophysics ; Mineralogy
WOS研究方向Geochemistry & Geophysics ; Mineralogy
资源类型期刊论文
条目标识符http://119.78.100.177/qdio/handle/2XILL650/133751
作者单位(1)OPEN UNIV, PLANT SCI RES INST, MILTON KEYNES MK7 6AA, BUCKS, ENGLAND;(2)OPEN UNIV, DEPT EARTH SCI, MILTON KEYNES MK7 6AA, BUCKS, ENGLAND;(3)OPEN UNIV, DEPT CHEM, MILTON KEYNES MK7 6AA, BUCKS, ENGLAND;(4)UNIV NEW S WALES, SCH PHYS, KENSINGTON, NSW 2003, AUSTRALIA
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Bland, PA,Kelley, SP,Berry, FJ,et al. Artificial weathering of the ordinary chondrite Allegan: Implications for the presence of Cl- as a structural component in akaganeite[J],1997,82(11-12):1187-1197.
APA Bland, PA,Kelley, SP,Berry, FJ,Cadogan, JM,&Pillinger, CT.(1997).Artificial weathering of the ordinary chondrite Allegan: Implications for the presence of Cl- as a structural component in akaganeite.AMERICAN MINERALOGIST,82(11-12),1187-1197.
MLA Bland, PA,et al."Artificial weathering of the ordinary chondrite Allegan: Implications for the presence of Cl- as a structural component in akaganeite".AMERICAN MINERALOGIST 82.11-12(1997):1187-1197.
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